Poly[[diaquabis{μ-4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoato-κ2O:N1′}copper(II)] dimethylformamide tetrasolvate]
In the title compound, {[Cu(C24H15N2O4)2(H2O)2]·4C3H7NO}n, the CuII ion, lying on an inversion center, is six-coordinated by two N atoms from two 4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoate (L) ligands, two deprotonated carboxylate O atoms from two other symmetry-related L...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813006430 |
| Summary: | In the title compound, {[Cu(C24H15N2O4)2(H2O)2]·4C3H7NO}n, the CuII ion, lying on an inversion center, is six-coordinated by two N atoms from two 4-[6-(4-carboxyphenyl)-4,4′-bipyridin-2-yl]benzoate (L) ligands, two deprotonated carboxylate O atoms from two other symmetry-related L ligands and two water molecules in a slightly distorted octahedral geometry. The CuII atoms are linked by the bridging ligands into a layer parallel to (101). The presence of intralayer O—H...O hydrogen bonds and π–π interactions between the pyridine and benzene rings [centroid–centroid distances = 3.808 (2) and 3.927 (2) Å] stabilizes the layer. Further O—H...O hydrogen bonds link the layers and the dimethylformamide solvent molecules. |
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| ISSN: | 1600-5368 |