4-[(E)-2,6-Dichlorobenzylideneamino]-3-{1-[4-(2-methylpropyl)phenyl]ethyl}-1H-1,2,4-triazole-5(4H)-thione

4-[(E)-2,6-Dichlorobenzylideneamino]-3-{1-[4-(2-methylpropyl)phenyl]ethyl}-1H-1,2,4-triazole-5(4H)-thione

In the title Schiff base compound, C21H22Cl2N4S, the triazole ring makes dihedral angles of 2.15 (11) and 87.48 (11)° with the 2,6-dichlorophenyl and methylpropylphenyl rings, respectively. Weak intramolecular C—H...S and C—H...Cl interactions generat...

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Main Authors: Hoong-Kun Fun, Suchada Chantrapromma, K. V. Sujith, P. S. Patil, A. Muralidharan, B. Kalluraya, S. M. Dharmaprakash
Format: Article
Language:English
Published: International Union of Crystallography 2008-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808021272
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spelling doaj-52b0bac94469407d8990b4a656ece3322020-11-25T00:53:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-08-01648o1503o150410.1107/S16005368080212724-[(E)-2,6-Dichlorobenzylideneamino]-3-{1-[4-(2-methylpropyl)phenyl]ethyl}-1H-1,2,4-triazole-5(4H)-thioneHoong-Kun FunSuchada ChantraprommaK. V. SujithP. S. PatilA. MuralidharanB. KallurayaS. M. DharmaprakashIn the title Schiff base compound, C21H22Cl2N4S, the triazole ring makes dihedral angles of 2.15 (11) and 87.48 (11)° with the 2,6-dichlorophenyl and methylpropylphenyl rings, respectively. Weak intramolecular C—H...S and C—H...Cl interactions generate S(6) and S(5) ring motifs, respectively. In the crystal structure, centrosymmetrically related molecules are linked into dimers by N—H...S hydrogen bonds. These dimers are arranged into sheets parallel to the ab plane and are stacked along the c axis. C—H...π interactions involving the methylpropylphenyl ring and π–π interactions involving the dichlorophenyl ring [centroid–centroid distance = 3.5865 (3) Å] are also observed.http://scripts.iucr.org/cgi-bin/paper?S1600536808021272
collection DOAJ
language English
format Article
sources DOAJ
author Hoong-Kun Fun
Suchada Chantrapromma
K. V. Sujith
P. S. Patil
A. Muralidharan
B. Kalluraya
S. M. Dharmaprakash
spellingShingle Hoong-Kun Fun
Suchada Chantrapromma
K. V. Sujith
P. S. Patil
A. Muralidharan
B. Kalluraya
S. M. Dharmaprakash
4-[(E)-2,6-Dichlorobenzylideneamino]-3-{1-[4-(2-methylpropyl)phenyl]ethyl}-1H-1,2,4-triazole-5(4H)-thione
Acta Crystallographica Section E
author_facet Hoong-Kun Fun
Suchada Chantrapromma
K. V. Sujith
P. S. Patil
A. Muralidharan
B. Kalluraya
S. M. Dharmaprakash
author_sort Hoong-Kun Fun
title 4-[(E)-2,6-Dichlorobenzylideneamino]-3-{1-[4-(2-methylpropyl)phenyl]ethyl}-1H-1,2,4-triazole-5(4H)-thione
title_short 4-[(E)-2,6-Dichlorobenzylideneamino]-3-{1-[4-(2-methylpropyl)phenyl]ethyl}-1H-1,2,4-triazole-5(4H)-thione
title_full 4-[(E)-2,6-Dichlorobenzylideneamino]-3-{1-[4-(2-methylpropyl)phenyl]ethyl}-1H-1,2,4-triazole-5(4H)-thione
title_fullStr 4-[(E)-2,6-Dichlorobenzylideneamino]-3-{1-[4-(2-methylpropyl)phenyl]ethyl}-1H-1,2,4-triazole-5(4H)-thione
title_full_unstemmed 4-[(E)-2,6-Dichlorobenzylideneamino]-3-{1-[4-(2-methylpropyl)phenyl]ethyl}-1H-1,2,4-triazole-5(4H)-thione
title_sort 4-[(e)-2,6-dichlorobenzylideneamino]-3-{1-[4-(2-methylpropyl)phenyl]ethyl}-1h-1,2,4-triazole-5(4h)-thione
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-08-01
description In the title Schiff base compound, C21H22Cl2N4S, the triazole ring makes dihedral angles of 2.15 (11) and 87.48 (11)° with the 2,6-dichlorophenyl and methylpropylphenyl rings, respectively. Weak intramolecular C—H...S and C—H...Cl interactions generate S(6) and S(5) ring motifs, respectively. In the crystal structure, centrosymmetrically related molecules are linked into dimers by N—H...S hydrogen bonds. These dimers are arranged into sheets parallel to the ab plane and are stacked along the c axis. C—H...π interactions involving the methylpropylphenyl ring and π–π interactions involving the dichlorophenyl ring [centroid–centroid distance = 3.5865 (3) Å] are also observed.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808021272
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