4-[(E)-2,6-Dichlorobenzylideneamino]-3-{1-[4-(2-methylpropyl)phenyl]ethyl}-1H-1,2,4-triazole-5(4H)-thione

In the title Schiff base compound, C21H22Cl2N4S, the triazole ring makes dihedral angles of 2.15 (11) and 87.48 (11)° with the 2,6-dichlorophenyl and methylpropylphenyl rings, respectively. Weak intramolecular C—H...S and C—H...Cl interactions generat...

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Bibliographic Details
Main Authors: Hoong-Kun Fun, Suchada Chantrapromma, K. V. Sujith, P. S. Patil, A. Muralidharan, B. Kalluraya, S. M. Dharmaprakash
Format: Article
Language:English
Published: International Union of Crystallography 2008-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808021272
Description
Summary:In the title Schiff base compound, C21H22Cl2N4S, the triazole ring makes dihedral angles of 2.15 (11) and 87.48 (11)° with the 2,6-dichlorophenyl and methylpropylphenyl rings, respectively. Weak intramolecular C—H...S and C—H...Cl interactions generate S(6) and S(5) ring motifs, respectively. In the crystal structure, centrosymmetrically related molecules are linked into dimers by N—H...S hydrogen bonds. These dimers are arranged into sheets parallel to the ab plane and are stacked along the c axis. C—H...π interactions involving the methylpropylphenyl ring and π–π interactions involving the dichlorophenyl ring [centroid–centroid distance = 3.5865 (3) Å] are also observed.
ISSN:1600-5368