1,1′,2,2′,3,3′,4,4′-Octamethylferrocenium 2,5-dibromo-4-hydroxy-3,6-dioxocyclohexa-1,4-dien-1-olate

In the title salt, octamethylferrocenium bromanilate, [Fe(C9H13)2](C6HBr2O4), the Fe atom and the bromanilate anion lie on a mirror plane. The octamethylferrocenium cation adopts an eclipsed conformation. An intramolecular O—H...O hydrogen bond is present in the bromanilate anion. In t...

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Bibliographic Details
Main Author: Tomoyuki Mochida
Format: Article
Language:English
Published: International Union of Crystallography 2011-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811025499
Description
Summary:In the title salt, octamethylferrocenium bromanilate, [Fe(C9H13)2](C6HBr2O4), the Fe atom and the bromanilate anion lie on a mirror plane. The octamethylferrocenium cation adopts an eclipsed conformation. An intramolecular O—H...O hydrogen bond is present in the bromanilate anion. In the crystal, the cations and anions are stacked alternately, forming a one-dimensional columnar structure along [010].
ISSN:1600-5368