Octa-coordinated alkaline earth metal–dinitrogen complexes M(N2)8 (M=Ca, Sr, Ba)

The study of main group complexes remains important to our fundamental understanding of main group element bonding and properties. Here the authors isolate and spectroscopically characterize a series of 8-coordinated alkaline earth metal–dinitrogen complexes M(N2)8 (M=Ca, Sr, Ba) in a low-temperatur...

Full description

Bibliographic Details
Main Authors:	Qian Wang, Sudip Pan, Shujun Lei, Jiaye Jin, Guohai Deng, Guanjun Wang, Lili Zhao, Mingfei Zhou, Gernot Frenking
Format:	Article
Language:	English
Published:	Nature Publishing Group 2019-07-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-019-11323-5

id	doaj-52518d44f7fc46d8a96d907116f94aea
record_format	Article
spelling	doaj-52518d44f7fc46d8a96d907116f94aea2021-05-11T12:01:36ZengNature Publishing GroupNature Communications2041-17232019-07-011011810.1038/s41467-019-11323-5Octa-coordinated alkaline earth metal–dinitrogen complexes M(N2)8 (M=Ca, Sr, Ba)Qian Wang0Sudip Pan1Shujun Lei2Jiaye Jin3Guohai Deng4Guanjun Wang5Lili Zhao6Mingfei Zhou7Gernot Frenking8Department of Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan UniversityInstitute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech UniversityDepartment of Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan UniversityDepartment of Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan UniversityDepartment of Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan UniversityDepartment of Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan UniversityInstitute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech UniversityDepartment of Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan UniversityInstitute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech UniversityThe study of main group complexes remains important to our fundamental understanding of main group element bonding and properties. Here the authors isolate and spectroscopically characterize a series of 8-coordinated alkaline earth metal–dinitrogen complexes M(N2)8 (M=Ca, Sr, Ba) in a low-temperature neon matrix.https://doi.org/10.1038/s41467-019-11323-5
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Qian Wang Sudip Pan Shujun Lei Jiaye Jin Guohai Deng Guanjun Wang Lili Zhao Mingfei Zhou Gernot Frenking
spellingShingle	Qian Wang Sudip Pan Shujun Lei Jiaye Jin Guohai Deng Guanjun Wang Lili Zhao Mingfei Zhou Gernot Frenking Octa-coordinated alkaline earth metal–dinitrogen complexes M(N2)8 (M=Ca, Sr, Ba) Nature Communications
author_facet	Qian Wang Sudip Pan Shujun Lei Jiaye Jin Guohai Deng Guanjun Wang Lili Zhao Mingfei Zhou Gernot Frenking
author_sort	Qian Wang
title	Octa-coordinated alkaline earth metal–dinitrogen complexes M(N2)8 (M=Ca, Sr, Ba)
title_short	Octa-coordinated alkaline earth metal–dinitrogen complexes M(N2)8 (M=Ca, Sr, Ba)
title_full	Octa-coordinated alkaline earth metal–dinitrogen complexes M(N2)8 (M=Ca, Sr, Ba)
title_fullStr	Octa-coordinated alkaline earth metal–dinitrogen complexes M(N2)8 (M=Ca, Sr, Ba)
title_full_unstemmed	Octa-coordinated alkaline earth metal–dinitrogen complexes M(N2)8 (M=Ca, Sr, Ba)
title_sort	octa-coordinated alkaline earth metal–dinitrogen complexes m(n2)8 (m=ca, sr, ba)
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2019-07-01
description	The study of main group complexes remains important to our fundamental understanding of main group element bonding and properties. Here the authors isolate and spectroscopically characterize a series of 8-coordinated alkaline earth metal–dinitrogen complexes M(N2)8 (M=Ca, Sr, Ba) in a low-temperature neon matrix.
url	https://doi.org/10.1038/s41467-019-11323-5
work_keys_str_mv	AT qianwang octacoordinatedalkalineearthmetaldinitrogencomplexesmn28mcasrba AT sudippan octacoordinatedalkalineearthmetaldinitrogencomplexesmn28mcasrba AT shujunlei octacoordinatedalkalineearthmetaldinitrogencomplexesmn28mcasrba AT jiayejin octacoordinatedalkalineearthmetaldinitrogencomplexesmn28mcasrba AT guohaideng octacoordinatedalkalineearthmetaldinitrogencomplexesmn28mcasrba AT guanjunwang octacoordinatedalkalineearthmetaldinitrogencomplexesmn28mcasrba AT lilizhao octacoordinatedalkalineearthmetaldinitrogencomplexesmn28mcasrba AT mingfeizhou octacoordinatedalkalineearthmetaldinitrogencomplexesmn28mcasrba AT gernotfrenking octacoordinatedalkalineearthmetaldinitrogencomplexesmn28mcasrba
_version_	1721445472611074048

Octa-coordinated alkaline earth metal–dinitrogen complexes M(N2)8 (M=Ca, Sr, Ba)

Similar Items