4Å molecular sieves catalyzed ring-opening of epoxides to 1,2-diacetates with acetic anhydride

4Å molecular sieves catalyzed ring-opening of epoxides to 1,2-diacetates with acetic anhydride

This study was aimed at highly stereoselective ring-opening of epoxides with acetic anhydride in the presence of molecular sieves 4Å as an efficient reagent. Yields of the 1,2-diacetates are uniformly good to excellent and the reagent may be recycled without the requirement for purification. High yi...

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Bibliographic Details
Main Authors: Masumeh Gilanizadeh, Behzad Zeynizadeh
Format: Article
Language:English
Published: Growing Science 2015-07-01
Series:Current Chemistry Letters
Subjects:
Acetic anhydride
1
2-Diacetate
Epoxide
Molecular sieves
Ring-opening
Online Access:http://www.growingscience.com/ccl/Vol4/ccl_2015_14.pdf
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spelling doaj-522762a4428f40919a34b5473ce273b62020-11-25T00:16:47ZengGrowing ScienceCurrent Chemistry Letters1927-72961927-730X2015-07-014415315810.5267/j.ccl.2015.6.0024Å molecular sieves catalyzed ring-opening of epoxides to 1,2-diacetates with acetic anhydrideMasumeh GilanizadehBehzad Zeynizadeh This study was aimed at highly stereoselective ring-opening of epoxides with acetic anhydride in the presence of molecular sieves 4Å as an efficient reagent. Yields of the 1,2-diacetates are uniformly good to excellent and the reagent may be recycled without the requirement for purification. High yields, short reaction times, ease of preparation and simple work-up procedure (filtration) are advantages of this method.http://www.growingscience.com/ccl/Vol4/ccl_2015_14.pdfAcetic anhydride12-DiacetateEpoxideMolecular sievesRing-opening
collection DOAJ
language English
format Article
sources DOAJ
author Masumeh Gilanizadeh
Behzad Zeynizadeh
spellingShingle Masumeh Gilanizadeh
Behzad Zeynizadeh
4Å molecular sieves catalyzed ring-opening of epoxides to 1,2-diacetates with acetic anhydride
Current Chemistry Letters
Acetic anhydride
1
2-Diacetate
Epoxide
Molecular sieves
Ring-opening
author_facet Masumeh Gilanizadeh
Behzad Zeynizadeh
author_sort Masumeh Gilanizadeh
title 4Å molecular sieves catalyzed ring-opening of epoxides to 1,2-diacetates with acetic anhydride
title_short 4Å molecular sieves catalyzed ring-opening of epoxides to 1,2-diacetates with acetic anhydride
title_full 4Å molecular sieves catalyzed ring-opening of epoxides to 1,2-diacetates with acetic anhydride
title_fullStr 4Å molecular sieves catalyzed ring-opening of epoxides to 1,2-diacetates with acetic anhydride
title_full_unstemmed 4Å molecular sieves catalyzed ring-opening of epoxides to 1,2-diacetates with acetic anhydride
title_sort 4å molecular sieves catalyzed ring-opening of epoxides to 1,2-diacetates with acetic anhydride
publisher Growing Science
series Current Chemistry Letters
issn 1927-7296
1927-730X
publishDate 2015-07-01
description This study was aimed at highly stereoselective ring-opening of epoxides with acetic anhydride in the presence of molecular sieves 4Å as an efficient reagent. Yields of the 1,2-diacetates are uniformly good to excellent and the reagent may be recycled without the requirement for purification. High yields, short reaction times, ease of preparation and simple work-up procedure (filtration) are advantages of this method.
topic Acetic anhydride
1
2-Diacetate
Epoxide
Molecular sieves
Ring-opening
url http://www.growingscience.com/ccl/Vol4/ccl_2015_14.pdf
work_keys_str_mv AT masumehgilanizadeh 4amolecularsievescatalyzedringopeningofepoxidesto12diacetateswithaceticanhydride
AT behzadzeynizadeh 4amolecularsievescatalyzedringopeningofepoxidesto12diacetateswithaceticanhydride
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