4Å molecular sieves catalyzed ring-opening of epoxides to 1,2-diacetates with acetic anhydride

This study was aimed at highly stereoselective ring-opening of epoxides with acetic anhydride in the presence of molecular sieves 4Å as an efficient reagent. Yields of the 1,2-diacetates are uniformly good to excellent and the reagent may be recycled without the requirement for purification. High yi...

Full description

Bibliographic Details
Main Authors: Masumeh Gilanizadeh, Behzad Zeynizadeh
Format: Article
Language:English
Published: Growing Science 2015-07-01
Series:Current Chemistry Letters
Subjects:
1
Online Access:http://www.growingscience.com/ccl/Vol4/ccl_2015_14.pdf
Description
Summary:This study was aimed at highly stereoselective ring-opening of epoxides with acetic anhydride in the presence of molecular sieves 4Å as an efficient reagent. Yields of the 1,2-diacetates are uniformly good to excellent and the reagent may be recycled without the requirement for purification. High yields, short reaction times, ease of preparation and simple work-up procedure (filtration) are advantages of this method.
ISSN:1927-7296
1927-730X