Visible-Light Photocatalyst to Remove Indoor Ozone under Ambient Condition

• Main Authors: Jia Quan Su, Yi-Chun Chang, Jeffrey C. S. Wu
• Format: Article
• Language: English
• Published: MDPI AG 2021-03-01
• Series: Catalysts
• Subjects: photocatalysis; ozone decomposition; strontium titanate; visible-light converter
• Online Access: https://www.mdpi.com/2073-4344/11/3/383

Ozone is a kind of hazardous gas in indoor areas and needs to be removed in order to protect the human respiratory system. Previous methods include physical adsorption, thermal treatment, electromagnetic radiation removal, catalysis and photocatalysis. However, they all have limited effects. This research introduced a novel milestone to remove indoor ozone by utilizing visible light photocatalysis technique under ambient condition. The modified sol–gel method was applied to prepare photocatalysts, strontium titanate (SrTiO₃) and rhodium-doped strontium titanate (SrTiO₃:Rh). In addition, the SrTiO₃:Rh was further immersed in N3 dye to improve its photocatalytic performance. Batch system and continuous-flow system were used to quantify the removal rate of ozone and to measure the conversions of ozone, respectively. The results showed that SrTiO₃:Rh possessed a higher ozone removal rate under a visible light condition compared with a commercial P25 TiO₂ catalyst. In addition, SrTiO₃:Rh based catalysts can also successfully perform visible light ozone photodecomposition in the continuous ozone flow system. Note that current ozone converters in aircraft utilize thermal-catalysts, which can only be operated at high temperature. This research reveals a promising catalysts and photo process, which can possibly replace the current aircraft ozone converters with visible-light driven converters, and boast higher performance under ambient condition.