Surface Changes of Selected Hardwoods Due to Weather Conditions

The study is focused on the surface changes of five hardwoods (oak, black locust, poplar, alder and maple) that were exposed to natural weathering for 24 months in the climatic conditions of Central Europe. Colour, roughness, visual and chemical changes of exposed surface structures were examined. T...

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Main Authors: Ivan Kubovský, Eliška Oberhofnerová, František Kačík, Miloš Pánek
Format: Article
Language:English
Published: MDPI AG 2018-09-01
Series:Forests
Subjects:
Online Access:http://www.mdpi.com/1999-4907/9/9/557
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spelling doaj-5186e68a63574f3d823ac6a2010638422020-11-24T21:17:48ZengMDPI AGForests1999-49072018-09-019955710.3390/f9090557f9090557Surface Changes of Selected Hardwoods Due to Weather ConditionsIvan Kubovský0Eliška Oberhofnerová1František Kačík2Miloš Pánek3Faculty of Wood Sciences and Technology, Technical University in Zvolen, T.G. Masaryka 24, 960 53 Zvolen, SlovakiaFaculty of Forestry and Wood Sciences, Czech University of Life Sciences in Prague, Kamýcká 129, 16521 Praha 6-Suchdol, Czech RepublicFaculty of Wood Sciences and Technology, Technical University in Zvolen, T.G. Masaryka 24, 960 53 Zvolen, SlovakiaFaculty of Forestry and Wood Sciences, Czech University of Life Sciences in Prague, Kamýcká 129, 16521 Praha 6-Suchdol, Czech RepublicThe study is focused on the surface changes of five hardwoods (oak, black locust, poplar, alder and maple) that were exposed to natural weathering for 24 months in the climatic conditions of Central Europe. Colour, roughness, visual and chemical changes of exposed surface structures were examined. The lowest total colour changes (ΔE*) were found for oak (23.77), the highest being recorded for maple (34.19). Roughness differences after 24-month exposure (ΔRa) showed minimal changes in poplar wood (9.41); the highest changes in roughness were found on the surface of alder (22.18). The presence of mould and blue stains was found on the surface of maple, alder and poplar. Chemical changes were characterized by lignin and hemicelluloses degradation. Decreases of both methoxy and carbonyl groups, cleavage of bonds in lignin and hemicelluloses, oxidation reaction and formation of new chromophores were observed. In the initial phases of the degradation process, the discoloration was related to chemical changes; in the longer period, the greying due to settling of dust particles and action of mould influenced the wood colour. The data were confirmed by confocal laser scanning microscopy. The obtained results revealed degradation processes of tested hardwood surfaces exposed to external environmental factors.http://www.mdpi.com/1999-4907/9/9/557chemical changescolour changesinfrared spectroscopyhardwoodsroughness
collection DOAJ
language English
format Article
sources DOAJ
author Ivan Kubovský
Eliška Oberhofnerová
František Kačík
Miloš Pánek
spellingShingle Ivan Kubovský
Eliška Oberhofnerová
František Kačík
Miloš Pánek
Surface Changes of Selected Hardwoods Due to Weather Conditions
Forests
chemical changes
colour changes
infrared spectroscopy
hardwoods
roughness
author_facet Ivan Kubovský
Eliška Oberhofnerová
František Kačík
Miloš Pánek
author_sort Ivan Kubovský
title Surface Changes of Selected Hardwoods Due to Weather Conditions
title_short Surface Changes of Selected Hardwoods Due to Weather Conditions
title_full Surface Changes of Selected Hardwoods Due to Weather Conditions
title_fullStr Surface Changes of Selected Hardwoods Due to Weather Conditions
title_full_unstemmed Surface Changes of Selected Hardwoods Due to Weather Conditions
title_sort surface changes of selected hardwoods due to weather conditions
publisher MDPI AG
series Forests
issn 1999-4907
publishDate 2018-09-01
description The study is focused on the surface changes of five hardwoods (oak, black locust, poplar, alder and maple) that were exposed to natural weathering for 24 months in the climatic conditions of Central Europe. Colour, roughness, visual and chemical changes of exposed surface structures were examined. The lowest total colour changes (ΔE*) were found for oak (23.77), the highest being recorded for maple (34.19). Roughness differences after 24-month exposure (ΔRa) showed minimal changes in poplar wood (9.41); the highest changes in roughness were found on the surface of alder (22.18). The presence of mould and blue stains was found on the surface of maple, alder and poplar. Chemical changes were characterized by lignin and hemicelluloses degradation. Decreases of both methoxy and carbonyl groups, cleavage of bonds in lignin and hemicelluloses, oxidation reaction and formation of new chromophores were observed. In the initial phases of the degradation process, the discoloration was related to chemical changes; in the longer period, the greying due to settling of dust particles and action of mould influenced the wood colour. The data were confirmed by confocal laser scanning microscopy. The obtained results revealed degradation processes of tested hardwood surfaces exposed to external environmental factors.
topic chemical changes
colour changes
infrared spectroscopy
hardwoods
roughness
url http://www.mdpi.com/1999-4907/9/9/557
work_keys_str_mv AT ivankubovsky surfacechangesofselectedhardwoodsduetoweatherconditions
AT eliskaoberhofnerova surfacechangesofselectedhardwoodsduetoweatherconditions
AT frantisekkacik surfacechangesofselectedhardwoodsduetoweatherconditions
AT milospanek surfacechangesofselectedhardwoodsduetoweatherconditions
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