Electrochemical determination of 5-dodecylsalicylaldoxime and 2′-hydroxy-5′-nonylacetophenone oxime in commercial extractants

A differential pulse voltammetric method using a hanging mercury drop electrode (HMDE) was optimized for the determination of 5-dodecylsalicylaldoxime in hydro-alcoholic solutions using factorial and central composite designs. The Taguchi design methodology was used to extend the formerly optimized...

Full description

Bibliographic Details
Main Authors:	Elizalde María P., Rúa Sol Del María, Huebra Marta, Menoyo Begoña
Format:	Article
Language:	English
Published:	Serbian Chemical Society 2017-01-01
Series:	Journal of the Serbian Chemical Society
Subjects:	voltammetry hydroxyoxime-based extractants factorial design
Online Access:	http://www.doiserbia.nb.rs/img/doi/0352-5139/2017/0352-51391700005E.pdf

id	doaj-51861fa9e5a84b27be71f8976abc20b3
record_format	Article
spelling	doaj-51861fa9e5a84b27be71f8976abc20b32020-11-25T00:21:06ZengSerbian Chemical Society Journal of the Serbian Chemical Society0352-51391820-74212017-01-0182441742510.2298/JSC160707005E0352-51391700005EElectrochemical determination of 5-dodecylsalicylaldoxime and 2′-hydroxy-5′-nonylacetophenone oxime in commercial extractantsElizalde María P.0Rúa Sol Del María1Huebra Marta2Menoyo Begoña3University of the Basque Country (UPV/EHU), Faculty of Science and Technology, Department of Analytical Chemistry, Bilbao, SpainUniversity of the Basque Country (UPV/EHU), Faculty of Science and Technology, Department of Analytical Chemistry, Bilbao, SpainUniversity of the Basque Country (UPV/EHU), Faculty of Science and Technology, Department of Analytical Chemistry, Bilbao, SpainUniversity of the Basque Country (UPV/EHU), Faculty of Science and Technology, Department of Analytical Chemistry, Bilbao, SpainA differential pulse voltammetric method using a hanging mercury drop electrode (HMDE) was optimized for the determination of 5-dodecylsalicylaldoxime in hydro-alcoholic solutions using factorial and central composite designs. The Taguchi design methodology was used to extend the formerly optimized method to the determination of 2′-hydroxy-5′-nonylacetophenone oxime. The method was successfully applied to quantify 5-dodecylsalicylaldoxime and 2′-hydroxy-5′-nonylacetophenone oxime in samples of commercial extractants over the concentration range 0.05–2.45 and 0.07–0.82 mg L-1, respectively, with detection limits of 0.034 and 0.019 mg L-1, respectively.http://www.doiserbia.nb.rs/img/doi/0352-5139/2017/0352-51391700005E.pdfvoltammetryhydroxyoxime-based extractantsfactorial design
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Elizalde María P. Rúa Sol Del María Huebra Marta Menoyo Begoña
spellingShingle	Elizalde María P. Rúa Sol Del María Huebra Marta Menoyo Begoña Electrochemical determination of 5-dodecylsalicylaldoxime and 2′-hydroxy-5′-nonylacetophenone oxime in commercial extractants Journal of the Serbian Chemical Society voltammetry hydroxyoxime-based extractants factorial design
author_facet	Elizalde María P. Rúa Sol Del María Huebra Marta Menoyo Begoña
author_sort	Elizalde María P.
title	Electrochemical determination of 5-dodecylsalicylaldoxime and 2′-hydroxy-5′-nonylacetophenone oxime in commercial extractants
title_short	Electrochemical determination of 5-dodecylsalicylaldoxime and 2′-hydroxy-5′-nonylacetophenone oxime in commercial extractants
title_full	Electrochemical determination of 5-dodecylsalicylaldoxime and 2′-hydroxy-5′-nonylacetophenone oxime in commercial extractants
title_fullStr	Electrochemical determination of 5-dodecylsalicylaldoxime and 2′-hydroxy-5′-nonylacetophenone oxime in commercial extractants
title_full_unstemmed	Electrochemical determination of 5-dodecylsalicylaldoxime and 2′-hydroxy-5′-nonylacetophenone oxime in commercial extractants
title_sort	electrochemical determination of 5-dodecylsalicylaldoxime and 2′-hydroxy-5′-nonylacetophenone oxime in commercial extractants
publisher	Serbian Chemical Society
series	Journal of the Serbian Chemical Society
issn	0352-5139 1820-7421
publishDate	2017-01-01
description	A differential pulse voltammetric method using a hanging mercury drop electrode (HMDE) was optimized for the determination of 5-dodecylsalicylaldoxime in hydro-alcoholic solutions using factorial and central composite designs. The Taguchi design methodology was used to extend the formerly optimized method to the determination of 2′-hydroxy-5′-nonylacetophenone oxime. The method was successfully applied to quantify 5-dodecylsalicylaldoxime and 2′-hydroxy-5′-nonylacetophenone oxime in samples of commercial extractants over the concentration range 0.05–2.45 and 0.07–0.82 mg L-1, respectively, with detection limits of 0.034 and 0.019 mg L-1, respectively.
topic	voltammetry hydroxyoxime-based extractants factorial design
url	http://www.doiserbia.nb.rs/img/doi/0352-5139/2017/0352-51391700005E.pdf
work_keys_str_mv	AT elizaldemariap electrochemicaldeterminationof5dodecylsalicylaldoximeand2hydroxy5nonylacetophenoneoximeincommercialextractants AT ruasoldelmaria electrochemicaldeterminationof5dodecylsalicylaldoximeand2hydroxy5nonylacetophenoneoximeincommercialextractants AT huebramarta electrochemicaldeterminationof5dodecylsalicylaldoximeand2hydroxy5nonylacetophenoneoximeincommercialextractants AT menoyobegona electrochemicaldeterminationof5dodecylsalicylaldoximeand2hydroxy5nonylacetophenoneoximeincommercialextractants
_version_	1725363959564861440

Electrochemical determination of 5-dodecylsalicylaldoxime and 2′-hydroxy-5′-nonylacetophenone oxime in commercial extractants

Similar Items