Study of the Structure of a Surface-porous Adsorbent using the Gas Chromatographic Version of the Molecular Probe method

Results are presented of structural studies of a silica-based surface-porous adsorbent. It is shown that a reliable estimate of the size of the surface micropores of this adsorbent can be obtained using the gas chromatographic version of the molecular probe method. This is based on a comparison of t...

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Main Authors: Yu.I. Tarasevich, A.I. Zhukova, E.V. Aksenenko, S.V. Bondarenko, O.V. Nazarenko
Format: Article
Language:English
Published: Hindawi - SAGE Publishing 1993-03-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/0263617499010001-413
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spelling doaj-51827b6c59354abe9d971c47fdbf35432021-04-02T13:32:25ZengHindawi - SAGE PublishingAdsorption Science & Technology0263-61742048-40381993-03-011010.1177/0263617499010001-413Study of the Structure of a Surface-porous Adsorbent using the Gas Chromatographic Version of the Molecular Probe methodYu.I. Tarasevich0A.I. Zhukova1E.V. Aksenenko2S.V. Bondarenko3O.V. Nazarenko4Institute of Colloid Chemistry and Chemistry of Water, Ukrainian Academy of Sciences, 42 Vernadsky Avenue, Kiev, 252680, Ukraine.Institute of Colloid Chemistry and Chemistry of Water, Ukrainian Academy of Sciences, 42 Vernadsky Avenue, Kiev, 252680, Ukraine.Institute of Colloid Chemistry and Chemistry of Water, Ukrainian Academy of Sciences, 42 Vernadsky Avenue, Kiev, 252680, Ukraine.Institute of Colloid Chemistry and Chemistry of Water, Ukrainian Academy of Sciences, 42 Vernadsky Avenue, Kiev, 252680, Ukraine.Institute of Colloid Chemistry and Chemistry of Water, Ukrainian Academy of Sciences, 42 Vernadsky Avenue, Kiev, 252680, Ukraine.Results are presented of structural studies of a silica-based surface-porous adsorbent. It is shown that a reliable estimate of the size of the surface micropores of this adsorbent can be obtained using the gas chromatographic version of the molecular probe method. This is based on a comparison of the thermodynamic properties for the adsorption of substances of known molecular size on the surface-porous adsorbent with those characteristic for the adsorption of the same substances on to a non-porous adsorbent of a similar chemical nature.https://doi.org/10.1177/0263617499010001-413
collection DOAJ
language English
format Article
sources DOAJ
author Yu.I. Tarasevich
A.I. Zhukova
E.V. Aksenenko
S.V. Bondarenko
O.V. Nazarenko
spellingShingle Yu.I. Tarasevich
A.I. Zhukova
E.V. Aksenenko
S.V. Bondarenko
O.V. Nazarenko
Study of the Structure of a Surface-porous Adsorbent using the Gas Chromatographic Version of the Molecular Probe method
Adsorption Science & Technology
author_facet Yu.I. Tarasevich
A.I. Zhukova
E.V. Aksenenko
S.V. Bondarenko
O.V. Nazarenko
author_sort Yu.I. Tarasevich
title Study of the Structure of a Surface-porous Adsorbent using the Gas Chromatographic Version of the Molecular Probe method
title_short Study of the Structure of a Surface-porous Adsorbent using the Gas Chromatographic Version of the Molecular Probe method
title_full Study of the Structure of a Surface-porous Adsorbent using the Gas Chromatographic Version of the Molecular Probe method
title_fullStr Study of the Structure of a Surface-porous Adsorbent using the Gas Chromatographic Version of the Molecular Probe method
title_full_unstemmed Study of the Structure of a Surface-porous Adsorbent using the Gas Chromatographic Version of the Molecular Probe method
title_sort study of the structure of a surface-porous adsorbent using the gas chromatographic version of the molecular probe method
publisher Hindawi - SAGE Publishing
series Adsorption Science & Technology
issn 0263-6174
2048-4038
publishDate 1993-03-01
description Results are presented of structural studies of a silica-based surface-porous adsorbent. It is shown that a reliable estimate of the size of the surface micropores of this adsorbent can be obtained using the gas chromatographic version of the molecular probe method. This is based on a comparison of the thermodynamic properties for the adsorption of substances of known molecular size on the surface-porous adsorbent with those characteristic for the adsorption of the same substances on to a non-porous adsorbent of a similar chemical nature.
url https://doi.org/10.1177/0263617499010001-413
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