Ethylenediammonium bis(5-methyl-3-oxo-2-phenyl-2,3-dihydropyrazol-1-ide): a hydrogen-bond-supported supramolecular ionic assembly

Ethylenediammonium bis(5-methyl-3-oxo-2-phenyl-2,3-dihydropyrazol-1-ide): a hydrogen-bond-supported supramolecular ionic assembly

The title compound, C2H10N22+·2C10H9N2O−, is composed of deprotonated 5-methyl-2-phenyl-1H-pyrazol-3(2H)-one anions (PMP−) and protonated ethylenediamine cations (H2en2+). The ethylenediammonium ion is located on a crystallographic inversion center. The dihedral angle be...

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Main Authors: Xin Wang, Xujie Yang, Daqi Wang, Xingyou Xu, Ruibo Xu
Format: Article
Language:English
Published: International Union of Crystallography 2008-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808026378
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spelling doaj-515cf49c117c4f299ffb48771bf62eb12020-11-24T21:32:33ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-09-01649o1808o180910.1107/S1600536808026378Ethylenediammonium bis(5-methyl-3-oxo-2-phenyl-2,3-dihydropyrazol-1-ide): a hydrogen-bond-supported supramolecular ionic assemblyXin WangXujie YangDaqi WangXingyou XuRuibo XuThe title compound, C2H10N22+·2C10H9N2O−, is composed of deprotonated 5-methyl-2-phenyl-1H-pyrazol-3(2H)-one anions (PMP−) and protonated ethylenediamine cations (H2en2+). The ethylenediammonium ion is located on a crystallographic inversion center. The dihedral angle between the phenyl and pyrazole rings is 39.73 (8)°. The two components are connected through N—H...O and N—H...N hydrogen bonds, forming an infinite three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536808026378
collection DOAJ
language English
format Article
sources DOAJ
author Xin Wang
Xujie Yang
Daqi Wang
Xingyou Xu
Ruibo Xu
spellingShingle Xin Wang
Xujie Yang
Daqi Wang
Xingyou Xu
Ruibo Xu
Ethylenediammonium bis(5-methyl-3-oxo-2-phenyl-2,3-dihydropyrazol-1-ide): a hydrogen-bond-supported supramolecular ionic assembly
Acta Crystallographica Section E
author_facet Xin Wang
Xujie Yang
Daqi Wang
Xingyou Xu
Ruibo Xu
author_sort Xin Wang
title Ethylenediammonium bis(5-methyl-3-oxo-2-phenyl-2,3-dihydropyrazol-1-ide): a hydrogen-bond-supported supramolecular ionic assembly
title_short Ethylenediammonium bis(5-methyl-3-oxo-2-phenyl-2,3-dihydropyrazol-1-ide): a hydrogen-bond-supported supramolecular ionic assembly
title_full Ethylenediammonium bis(5-methyl-3-oxo-2-phenyl-2,3-dihydropyrazol-1-ide): a hydrogen-bond-supported supramolecular ionic assembly
title_fullStr Ethylenediammonium bis(5-methyl-3-oxo-2-phenyl-2,3-dihydropyrazol-1-ide): a hydrogen-bond-supported supramolecular ionic assembly
title_full_unstemmed Ethylenediammonium bis(5-methyl-3-oxo-2-phenyl-2,3-dihydropyrazol-1-ide): a hydrogen-bond-supported supramolecular ionic assembly
title_sort ethylenediammonium bis(5-methyl-3-oxo-2-phenyl-2,3-dihydropyrazol-1-ide): a hydrogen-bond-supported supramolecular ionic assembly
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-09-01
description The title compound, C2H10N22+·2C10H9N2O−, is composed of deprotonated 5-methyl-2-phenyl-1H-pyrazol-3(2H)-one anions (PMP−) and protonated ethylenediamine cations (H2en2+). The ethylenediammonium ion is located on a crystallographic inversion center. The dihedral angle between the phenyl and pyrazole rings is 39.73 (8)°. The two components are connected through N—H...O and N—H...N hydrogen bonds, forming an infinite three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808026378
work_keys_str_mv AT xinwang ethylenediammoniumbis5methyl3oxo2phenyl23dihydropyrazol1ideahydrogenbondsupportedsupramolecularionicassembly
AT xujieyang ethylenediammoniumbis5methyl3oxo2phenyl23dihydropyrazol1ideahydrogenbondsupportedsupramolecularionicassembly
AT daqiwang ethylenediammoniumbis5methyl3oxo2phenyl23dihydropyrazol1ideahydrogenbondsupportedsupramolecularionicassembly
AT xingyouxu ethylenediammoniumbis5methyl3oxo2phenyl23dihydropyrazol1ideahydrogenbondsupportedsupramolecularionicassembly
AT ruiboxu ethylenediammoniumbis5methyl3oxo2phenyl23dihydropyrazol1ideahydrogenbondsupportedsupramolecularionicassembly
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