Transition metal complexes with thiosemicarbazide-based ligands, part 47: Synthesis, physicochemical and voltammetric characterization of iron(III) complexes with pyridoxal semi-, thiosemi- and S-meth
The reaction of warm EtOH solutions of FeX3.nH2O (X=Cl, NO3) with tridentate ONX (X=O, S, N) pyridoxal semi-, thiosemi- and S-methylisothiosemicabazones (H2L1, H2L2, H2L3, respectively) yielded high-spin octahedral mono- and bis(ligand) complexes of the formula [Fe(H2L1-3)Cl2(H2O)]Cl,[Fe(HL1,2)2]Cl....
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Serbian Chemical Society
2003-01-01
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| Series: | Journal of the Serbian Chemical Society |
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| Online Access: | http://www.doiserbia.nb.rs/img/doi/0352-5139/2003/0352-51390312929J.pdf |
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doaj-50ab040ec6494adca36d25ece77ac4b22020-12-24T12:17:44ZengSerbian Chemical Society Journal of the Serbian Chemical Society0352-51391820-74212003-01-01681292994210.2298/JSC0312929J0352-51390312929JTransition metal complexes with thiosemicarbazide-based ligands, part 47: Synthesis, physicochemical and voltammetric characterization of iron(III) complexes with pyridoxal semi-, thiosemi- and S-methJevtović Violeta S.0Jovanović Ljiljana S.1Leovac Vukadin M.2Bjelica Luka J.3Faculty of Science, University of Novi Sad, Trg D. Obradovića 3, 21000 Novi Sad, Serbia and MontenegroFaculty of Science, University of Novi Sad, Trg D. Obradovića 3, 21000 Novi Sad, Serbia and MontenegroFaculty of Science, University of Novi Sad, Trg D. Obradovića 3, 21000 Novi Sad, Serbia and MontenegroFaculty of Science, University of Novi Sad, Trg D. Obradovića 3, 21000 Novi Sad, Serbia and MontenegroThe reaction of warm EtOH solutions of FeX3.nH2O (X=Cl, NO3) with tridentate ONX (X=O, S, N) pyridoxal semi-, thiosemi- and S-methylisothiosemicabazones (H2L1, H2L2, H2L3, respectively) yielded high-spin octahedral mono- and bis(ligand) complexes of the formula [Fe(H2L1-3)Cl2(H2O)]Cl,[Fe(HL1,2)2]Cl.nH2O and [Fe(H2L3)(HL3)]NO3)2.H2O. The compounds were characterized by elemental analysis, conductometric and magnetochemical measurements, IR and UV-Vis spectra. Besides, a detailed voltammetric study of the complexes was carried out in DMF solution in the presence of several supporting electrolytes, to characterize the nature of the electrode processes and solution equilibria.http://www.doiserbia.nb.rs/img/doi/0352-5139/2003/0352-51390312929J.pdfiron(iii) complexespyridoxal semi-thiosemi- and isothiosemicarba- zonesphysicochemical and voltammetric studies |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Jevtović Violeta S. Jovanović Ljiljana S. Leovac Vukadin M. Bjelica Luka J. |
| spellingShingle |
Jevtović Violeta S. Jovanović Ljiljana S. Leovac Vukadin M. Bjelica Luka J. Transition metal complexes with thiosemicarbazide-based ligands, part 47: Synthesis, physicochemical and voltammetric characterization of iron(III) complexes with pyridoxal semi-, thiosemi- and S-meth Journal of the Serbian Chemical Society iron(iii) complexes pyridoxal semi- thiosemi- and isothiosemicarba- zones physicochemical and voltammetric studies |
| author_facet |
Jevtović Violeta S. Jovanović Ljiljana S. Leovac Vukadin M. Bjelica Luka J. |
| author_sort |
Jevtović Violeta S. |
| title |
Transition metal complexes with thiosemicarbazide-based ligands, part 47: Synthesis, physicochemical and voltammetric characterization of iron(III) complexes with pyridoxal semi-, thiosemi- and S-meth |
| title_short |
Transition metal complexes with thiosemicarbazide-based ligands, part 47: Synthesis, physicochemical and voltammetric characterization of iron(III) complexes with pyridoxal semi-, thiosemi- and S-meth |
| title_full |
Transition metal complexes with thiosemicarbazide-based ligands, part 47: Synthesis, physicochemical and voltammetric characterization of iron(III) complexes with pyridoxal semi-, thiosemi- and S-meth |
| title_fullStr |
Transition metal complexes with thiosemicarbazide-based ligands, part 47: Synthesis, physicochemical and voltammetric characterization of iron(III) complexes with pyridoxal semi-, thiosemi- and S-meth |
| title_full_unstemmed |
Transition metal complexes with thiosemicarbazide-based ligands, part 47: Synthesis, physicochemical and voltammetric characterization of iron(III) complexes with pyridoxal semi-, thiosemi- and S-meth |
| title_sort |
transition metal complexes with thiosemicarbazide-based ligands, part 47: synthesis, physicochemical and voltammetric characterization of iron(iii) complexes with pyridoxal semi-, thiosemi- and s-meth |
| publisher |
Serbian Chemical Society |
| series |
Journal of the Serbian Chemical Society |
| issn |
0352-5139 1820-7421 |
| publishDate |
2003-01-01 |
| description |
The reaction of warm EtOH solutions of FeX3.nH2O (X=Cl, NO3) with tridentate ONX (X=O, S, N) pyridoxal semi-, thiosemi- and S-methylisothiosemicabazones (H2L1, H2L2, H2L3, respectively) yielded high-spin octahedral mono- and bis(ligand) complexes of the formula [Fe(H2L1-3)Cl2(H2O)]Cl,[Fe(HL1,2)2]Cl.nH2O and [Fe(H2L3)(HL3)]NO3)2.H2O. The compounds were characterized by elemental analysis, conductometric and magnetochemical measurements, IR and UV-Vis spectra. Besides, a detailed voltammetric study of the complexes was carried out in DMF solution in the presence of several supporting electrolytes, to characterize the nature of the electrode processes and solution equilibria. |
| topic |
iron(iii) complexes pyridoxal semi- thiosemi- and isothiosemicarba- zones physicochemical and voltammetric studies |
| url |
http://www.doiserbia.nb.rs/img/doi/0352-5139/2003/0352-51390312929J.pdf |
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