Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)]

Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)]

In the title complex, [Sn2(C7H7)4(C10H8N2O3)2(C2H5OH)2], the Sn(IV) atom is seven-coordinated in a distorted pentagonal–bipyramidal geometry by three O atoms and one N atom from the pyruvate benzoyl hydrazone ligand, one ethanol O atom and two axial C atoms from trans-benzyl groups, th...

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Main Authors: Shaojun Sun, Jie Yang
Format: Article
Language:English
Published: International Union of Crystallography 2011-05-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811011937
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spelling doaj-50a292f24e324070ac610ce018faf1ed2020-11-24T21:29:02ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-05-01675m544m54410.1107/S1600536811011937Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)]Shaojun SunJie YangIn the title complex, [Sn2(C7H7)4(C10H8N2O3)2(C2H5OH)2], the Sn(IV) atom is seven-coordinated in a distorted pentagonal–bipyramidal geometry by three O atoms and one N atom from the pyruvate benzoyl hydrazone ligand, one ethanol O atom and two axial C atoms from trans-benzyl groups, thus forming a dimeric molecule (overline{1} symmetry) via weak Sn—O interactions. The C atoms of one phenyl ring and the ethanol molecule are disordered over two sets of sites with site-occupancy factors of 0.57 (5):0.43 (5) and 0.79 (2):0.21 (2), respectively. Intermolecular O—H...O hydrogen bonds stabilize the crystal structure. http://scripts.iucr.org/cgi-bin/paper?S1600536811011937
collection DOAJ
language English
format Article
sources DOAJ
author Shaojun Sun
Jie Yang
spellingShingle Shaojun Sun
Jie Yang
Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)]
Acta Crystallographica Section E
author_facet Shaojun Sun
Jie Yang
author_sort Shaojun Sun
title Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)]
title_short Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)]
title_full Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)]
title_fullStr Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)]
title_full_unstemmed Bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(IV)]
title_sort bis(μ-2-{[oxido(phenyl)methylidene]hydrazinylidene}propanoato)bis[dibenzyl(ethanol)tin(iv)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-05-01
description In the title complex, [Sn2(C7H7)4(C10H8N2O3)2(C2H5OH)2], the Sn(IV) atom is seven-coordinated in a distorted pentagonal–bipyramidal geometry by three O atoms and one N atom from the pyruvate benzoyl hydrazone ligand, one ethanol O atom and two axial C atoms from trans-benzyl groups, thus forming a dimeric molecule (overline{1} symmetry) via weak Sn—O interactions. The C atoms of one phenyl ring and the ethanol molecule are disordered over two sets of sites with site-occupancy factors of 0.57 (5):0.43 (5) and 0.79 (2):0.21 (2), respectively. Intermolecular O—H...O hydrogen bonds stabilize the crystal structure.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811011937
work_keys_str_mv AT shaojunsun bisamp9562oxidophenylmethylidenehydrazinylidenepropanoatobisdibenzylethanoltiniv
AT jieyang bisamp9562oxidophenylmethylidenehydrazinylidenepropanoatobisdibenzylethanoltiniv
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