Photoinduced Electron Spin Resonance Phenomenon in α-Cr2O3 Nanospheres
The photoinduced phenomenon in α-Cr2O3 nanoscaled spherical particles was investigated in the temperature range of 150 up to 315 K. An X-band electron-spin resonance spectrometry was employed to probe the magnetic behavior in α-Cr2O3 under an IR illumination in the nanosecond regime....
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Hindawi Limited
2015-01-01
|
| Series: | Journal of Nanomaterials |
| Online Access: | http://dx.doi.org/10.1155/2015/831065 |
| Summary: | The photoinduced phenomenon in α-Cr2O3 nanoscaled spherical particles was investigated in the temperature range of 150 up to 315 K. An X-band electron-spin resonance spectrometry was employed to probe the magnetic behavior in α-Cr2O3 under an IR illumination in the nanosecond regime. The photoinduced effect on both low and high field ESR signals appears above 280 K and is remarkably enhanced just below Néel temperature TN. Such a photoinduced ESR phenomenon disappears in a reproducible way in the paramagnetic insulating state which occurs above TN of crystalline α-Cr2O3. In the antiferromagnetic phase, that is, below TN, the shift of the low field absorption could be attributed to the interaction of the light with specific Cr3+ ions located in strongly distorted sites correlated to strong ligand-field effect. |
|---|---|
| ISSN: | 1687-4110 1687-4129 |