Synthesis, Crystal Structure, and Electroconducting Properties of a 1D Mixed-Valence Cu(I)–Cu(II) Coordination Polymer with a Dicyclohexyl Dithiocarbamate Ligand

A new mixed-valence Cu(I)–Cu(II) 1D coordination polymer, [CuI4CuIIBr4(Cy2dtc)2]n, with an infinite chain structure is synthesized by the reaction of Cu(Cy2dtc)2 (Cy2dtc− = dicyclohexyl dithiocarbamate, C13H22NS2) with CuBr·S(CH3)2. The as-synthesized polymer consists of mononuclear copper(II) unit...

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Main Authors:	Kenji Nakatani, Kento Himoto, Yuki Kono, Yuuki Nakahashi, Haruho Anma, Takashi Okubo, Masahiko Maekawa, Takayoshi Kuroda-Sowa
Format:	Article
Language:	English
Published:	MDPI AG 2015-04-01
Series:	Crystals
Subjects:	copper complex mixed-valence coordination polymer
Online Access:	http://www.mdpi.com/2073-4352/5/2/215

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spelling	doaj-50884e2272744384980e40ebcb1c804d2020-11-24T22:51:33ZengMDPI AGCrystals2073-43522015-04-015221522510.3390/cryst5020215cryst5020215Synthesis, Crystal Structure, and Electroconducting Properties of a 1D Mixed-Valence Cu(I)–Cu(II) Coordination Polymer with a Dicyclohexyl Dithiocarbamate LigandKenji Nakatani0Kento Himoto1Yuki Kono2Yuuki Nakahashi3Haruho Anma4Takashi Okubo5Masahiko Maekawa6Takayoshi Kuroda-Sowa7School of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka-shi, Osaka 577-8502, JapanSchool of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka-shi, Osaka 577-8502, JapanSchool of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka-shi, Osaka 577-8502, JapanSchool of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka-shi, Osaka 577-8502, JapanSchool of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka-shi, Osaka 577-8502, JapanSchool of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka-shi, Osaka 577-8502, JapanSchool of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka-shi, Osaka 577-8502, JapanSchool of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka-shi, Osaka 577-8502, JapanA new mixed-valence Cu(I)–Cu(II) 1D coordination polymer, [CuI4CuIIBr4(Cy2dtc)2]n, with an infinite chain structure is synthesized by the reaction of Cu(Cy2dtc)2 (Cy2dtc− = dicyclohexyl dithiocarbamate, C13H22NS2) with CuBr·S(CH3)2. The as-synthesized polymer consists of mononuclear copper(II) units of CuII(Cy2dtc)2 and tetranuclear copper(I) cluster units, CuI4Br4. In the cluster unit, all the CuI ions have distorted trigonal pyramidal coordination geometries, and the CuI–CuI or CuI–CuII distances between the nearest copper ions are shorter than the sum of van der Waals radii for Cu–Cu.http://www.mdpi.com/2073-4352/5/2/215copper complexmixed-valencecoordination polymer
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Kenji Nakatani Kento Himoto Yuki Kono Yuuki Nakahashi Haruho Anma Takashi Okubo Masahiko Maekawa Takayoshi Kuroda-Sowa
spellingShingle	Kenji Nakatani Kento Himoto Yuki Kono Yuuki Nakahashi Haruho Anma Takashi Okubo Masahiko Maekawa Takayoshi Kuroda-Sowa Synthesis, Crystal Structure, and Electroconducting Properties of a 1D Mixed-Valence Cu(I)–Cu(II) Coordination Polymer with a Dicyclohexyl Dithiocarbamate Ligand Crystals copper complex mixed-valence coordination polymer
author_facet	Kenji Nakatani Kento Himoto Yuki Kono Yuuki Nakahashi Haruho Anma Takashi Okubo Masahiko Maekawa Takayoshi Kuroda-Sowa
author_sort	Kenji Nakatani
title	Synthesis, Crystal Structure, and Electroconducting Properties of a 1D Mixed-Valence Cu(I)–Cu(II) Coordination Polymer with a Dicyclohexyl Dithiocarbamate Ligand
title_short	Synthesis, Crystal Structure, and Electroconducting Properties of a 1D Mixed-Valence Cu(I)–Cu(II) Coordination Polymer with a Dicyclohexyl Dithiocarbamate Ligand
title_full	Synthesis, Crystal Structure, and Electroconducting Properties of a 1D Mixed-Valence Cu(I)–Cu(II) Coordination Polymer with a Dicyclohexyl Dithiocarbamate Ligand
title_fullStr	Synthesis, Crystal Structure, and Electroconducting Properties of a 1D Mixed-Valence Cu(I)–Cu(II) Coordination Polymer with a Dicyclohexyl Dithiocarbamate Ligand
title_full_unstemmed	Synthesis, Crystal Structure, and Electroconducting Properties of a 1D Mixed-Valence Cu(I)–Cu(II) Coordination Polymer with a Dicyclohexyl Dithiocarbamate Ligand
title_sort	synthesis, crystal structure, and electroconducting properties of a 1d mixed-valence cu(i)–cu(ii) coordination polymer with a dicyclohexyl dithiocarbamate ligand
publisher	MDPI AG
series	Crystals
issn	2073-4352
publishDate	2015-04-01
description	A new mixed-valence Cu(I)–Cu(II) 1D coordination polymer, [CuI4CuIIBr4(Cy2dtc)2]n, with an infinite chain structure is synthesized by the reaction of Cu(Cy2dtc)2 (Cy2dtc− = dicyclohexyl dithiocarbamate, C13H22NS2) with CuBr·S(CH3)2. The as-synthesized polymer consists of mononuclear copper(II) units of CuII(Cy2dtc)2 and tetranuclear copper(I) cluster units, CuI4Br4. In the cluster unit, all the CuI ions have distorted trigonal pyramidal coordination geometries, and the CuI–CuI or CuI–CuII distances between the nearest copper ions are shorter than the sum of van der Waals radii for Cu–Cu.
topic	copper complex mixed-valence coordination polymer
url	http://www.mdpi.com/2073-4352/5/2/215
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Synthesis, Crystal Structure, and Electroconducting Properties of a 1D Mixed-Valence Cu(I)–Cu(II) Coordination Polymer with a Dicyclohexyl Dithiocarbamate Ligand

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