Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(4-hydroxyphenyl)prop-2-en-1-one] N,N-dimethylformamide disolvate
In the bischalcone molecule of the title compound, C24H18O4·2C3H7NO, the central benzene and terminal hydroxyphenyl rings form a dihedral angle of 14.28 (11)° and the central C=C double bond adopts a trans configuration. In the crystal, the bischalcone and solvate molecules are interconnected via O—...
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International Union of Crystallography
2018-06-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989018007429 |
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doaj-5033344fd115440d9f148f0d9b1cbc002020-11-24T21:39:02ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902018-06-0174683583910.1107/S2056989018007429xu5924Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(4-hydroxyphenyl)prop-2-en-1-one] N,N-dimethylformamide disolvateHuey Chong Kwong0Ai Jia Sim1C. S. Chidan Kumar2Ching Kheng Quah3Suchada Chantrapromma4S. Naveen5Ismail Warad6School of Chemical Sciences, Universiti Sains Malaysia, Penang 11800 USM, MalaysiaX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, MalaysiaDepartment of Engineering Chemistry, Vidya Vikas Institute of Engineering & Technology, Visvesvaraya Technological University, Alanahally, Mysuru 570028, Karnataka, IndiaX-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, MalaysiaDepartment of Chemistry, Faculty of Science, Prince of Songkla University, Hat-Yai, Songkhla 90112, ThailandDepartment of Physics, School of Engineering and Technology, Jain University, Bangalore 562 112, IndiaDepartment of Chemistry, Science College, An-Najah National University, PO Box 7, Nablus, West Bank, Palestinian TerritoriesIn the bischalcone molecule of the title compound, C24H18O4·2C3H7NO, the central benzene and terminal hydroxyphenyl rings form a dihedral angle of 14.28 (11)° and the central C=C double bond adopts a trans configuration. In the crystal, the bischalcone and solvate molecules are interconnected via O—H...O hydrogen bonds, which were investigated by Hirshfeld surface analysis. Solid-state fluorescence was measured at λex = 4400 Å. The emission wavelength appeared at 5510 Å, which corresponds to yellow light and the solid-state fluorescence quantum yield (Ff) is 0.18.http://scripts.iucr.org/cgi-bin/paper?S2056989018007429bischalconespectroscopycentrosymmetricHirshfeld surfacefluorescencecrystal structure |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Huey Chong Kwong Ai Jia Sim C. S. Chidan Kumar Ching Kheng Quah Suchada Chantrapromma S. Naveen Ismail Warad |
| spellingShingle |
Huey Chong Kwong Ai Jia Sim C. S. Chidan Kumar Ching Kheng Quah Suchada Chantrapromma S. Naveen Ismail Warad Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(4-hydroxyphenyl)prop-2-en-1-one] N,N-dimethylformamide disolvate Acta Crystallographica Section E: Crystallographic Communications bischalcone spectroscopy centrosymmetric Hirshfeld surface fluorescence crystal structure |
| author_facet |
Huey Chong Kwong Ai Jia Sim C. S. Chidan Kumar Ching Kheng Quah Suchada Chantrapromma S. Naveen Ismail Warad |
| author_sort |
Huey Chong Kwong |
| title |
Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(4-hydroxyphenyl)prop-2-en-1-one] N,N-dimethylformamide disolvate |
| title_short |
Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(4-hydroxyphenyl)prop-2-en-1-one] N,N-dimethylformamide disolvate |
| title_full |
Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(4-hydroxyphenyl)prop-2-en-1-one] N,N-dimethylformamide disolvate |
| title_fullStr |
Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(4-hydroxyphenyl)prop-2-en-1-one] N,N-dimethylformamide disolvate |
| title_full_unstemmed |
Synthesis, spectroscopic and Hirshfeld surface analysis and fluorescence studies of (2E,2′E)-3,3′-(1,4-phenylene)bis[1-(4-hydroxyphenyl)prop-2-en-1-one] N,N-dimethylformamide disolvate |
| title_sort |
synthesis, spectroscopic and hirshfeld surface analysis and fluorescence studies of (2e,2′e)-3,3′-(1,4-phenylene)bis[1-(4-hydroxyphenyl)prop-2-en-1-one] n,n-dimethylformamide disolvate |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E: Crystallographic Communications |
| issn |
2056-9890 |
| publishDate |
2018-06-01 |
| description |
In the bischalcone molecule of the title compound, C24H18O4·2C3H7NO, the central benzene and terminal hydroxyphenyl rings form a dihedral angle of 14.28 (11)° and the central C=C double bond adopts a trans configuration. In the crystal, the bischalcone and solvate molecules are interconnected via O—H...O hydrogen bonds, which were investigated by Hirshfeld surface analysis. Solid-state fluorescence was measured at λex = 4400 Å. The emission wavelength appeared at 5510 Å, which corresponds to yellow light and the solid-state fluorescence quantum yield (Ff) is 0.18. |
| topic |
bischalcone spectroscopy centrosymmetric Hirshfeld surface fluorescence crystal structure |
| url |
http://scripts.iucr.org/cgi-bin/paper?S2056989018007429 |
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