Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-κS)tin(IV)–tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-κS)tin(IV) (1/1)

Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-κS)tin(IV)–tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-κS)tin(IV) (1/1)

Tris(2-chlorobenzyl)tin hydroxide condenses with 3-mercapto-1,2,4-triazole to form the 1:1 cocrystal of the title compound, [Sn(C7H6Cl)3(C2H2N3S)]. The asymmetric unit contains two molecules which differ only in the position of the nitrogen-bound H atom of the triazole ring; one molecule is linked t...

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Main Authors: Thy Chun Keng, Kong Mun Lo, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2010-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053681003076X
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spelling doaj-500c617920784b4e942d6bb48f49573c2020-11-24T21:26:28ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-09-01669m1064m106410.1107/S160053681003076XTris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-κS)tin(IV)–tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-κS)tin(IV) (1/1)Thy Chun KengKong Mun LoSeik Weng NgTris(2-chlorobenzyl)tin hydroxide condenses with 3-mercapto-1,2,4-triazole to form the 1:1 cocrystal of the title compound, [Sn(C7H6Cl)3(C2H2N3S)]. The asymmetric unit contains two molecules which differ only in the position of the nitrogen-bound H atom of the triazole ring; one molecule is linked to the other molecule by an N—H...N hydrogen bond. In the second molecule, two of the chlorobenzyl units are disordered over two positions in a 0.73 (1):0.27 (1) ratio. The Sn atom in both molecules shows a distorted tetrahedral SnSC3 coordination. http://scripts.iucr.org/cgi-bin/paper?S160053681003076X
collection DOAJ
language English
format Article
sources DOAJ
author Thy Chun Keng
Kong Mun Lo
Seik Weng Ng
spellingShingle Thy Chun Keng
Kong Mun Lo
Seik Weng Ng
Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-κS)tin(IV)–tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-κS)tin(IV) (1/1)
Acta Crystallographica Section E
author_facet Thy Chun Keng
Kong Mun Lo
Seik Weng Ng
author_sort Thy Chun Keng
title Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-κS)tin(IV)–tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-κS)tin(IV) (1/1)
title_short Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-κS)tin(IV)–tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-κS)tin(IV) (1/1)
title_full Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-κS)tin(IV)–tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-κS)tin(IV) (1/1)
title_fullStr Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-κS)tin(IV)–tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-κS)tin(IV) (1/1)
title_full_unstemmed Tris(2-chlorobenzyl)(1H-1,2,4-triazole-5-thiolato-κS)tin(IV)–tris(2-chlorobenzyl)(4H-1,2,4-triazole-3-thiolato-κS)tin(IV) (1/1)
title_sort tris(2-chlorobenzyl)(1h-1,2,4-triazole-5-thiolato-κs)tin(iv)–tris(2-chlorobenzyl)(4h-1,2,4-triazole-3-thiolato-κs)tin(iv) (1/1)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-09-01
description Tris(2-chlorobenzyl)tin hydroxide condenses with 3-mercapto-1,2,4-triazole to form the 1:1 cocrystal of the title compound, [Sn(C7H6Cl)3(C2H2N3S)]. The asymmetric unit contains two molecules which differ only in the position of the nitrogen-bound H atom of the triazole ring; one molecule is linked to the other molecule by an N—H...N hydrogen bond. In the second molecule, two of the chlorobenzyl units are disordered over two positions in a 0.73 (1):0.27 (1) ratio. The Sn atom in both molecules shows a distorted tetrahedral SnSC3 coordination.
url http://scripts.iucr.org/cgi-bin/paper?S160053681003076X
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AT kongmunlo tris2chlorobenzyl1h124triazole5thiolatoamp954stinivamp8211tris2chlorobenzyl4h124triazole3thiolatoamp954stiniv11
AT seikwengng tris2chlorobenzyl1h124triazole5thiolatoamp954stinivamp8211tris2chlorobenzyl4h124triazole3thiolatoamp954stiniv11
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