2-[5-(Pyridin-2-yl)-1,3,4-thiadiazol-2-yl]pyridin-1-ium perchlorate
The cation of the title molecular salt, C12H9N4S+·ClO4−, is approximately planar, with the pyridine and pyridinium rings being inclined to the central thiadiazole ring by 6.51 (9) and 9.13 (9)°, respectively. The dihedral angle between the pyridine and pyridinium rings is 12.91 (10)°. In the crystal...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2017-03-01
|
| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314617004655 |
| id |
doaj-4fbf9b0895c140eb89de1c5f9822ecd2 |
|---|---|
| record_format |
Article |
| spelling |
doaj-4fbf9b0895c140eb89de1c5f9822ecd22020-11-25T00:32:54ZengInternational Union of CrystallographyIUCrData2414-31462017-03-0123x17046510.1107/S2414314617004655su41432-[5-(Pyridin-2-yl)-1,3,4-thiadiazol-2-yl]pyridin-1-ium perchlorateAbdelhakim Laachir0Fouad Bentiss1Salaheddine Guesmi2Mohamed Saadi3Lahcen El Ammari4Laboratoire de Chimie de Coordination et d'Analytique (LCCA), Faculté des Sciences, Université Chouaib Doukkali, BP 20, M-24000 El Jadida, MoroccoLaboratoire de Catalyse et de Corrosion de Matériaux (LCCM), Faculté des Sciences, Université Chouaib Doukkali, BP 20, M-24000 El Jadida, MoroccoLaboratoire de Chimie de Coordination et d'Analytique (LCCA), Faculté des Sciences, Université Chouaib Doukkali, BP 20, M-24000 El Jadida, MoroccoLaboratoire de Chimie du Solide Appliquée, Faculty of Sciences, Mohammed V University in Rabat, Avenue Ibn Batouta, BP 1014, Rabat, MoroccoLaboratoire de Chimie du Solide Appliquée, Faculty of Sciences, Mohammed V University in Rabat, Avenue Ibn Batouta, BP 1014, Rabat, MoroccoThe cation of the title molecular salt, C12H9N4S+·ClO4−, is approximately planar, with the pyridine and pyridinium rings being inclined to the central thiadiazole ring by 6.51 (9) and 9.13 (9)°, respectively. The dihedral angle between the pyridine and pyridinium rings is 12.91 (10)°. In the crystal, the cations are linked by N—H...O and C—H...O hydrogen bonds, involving the perchlorate anion, forming chains propagating along the [100] direction. The chains are linked by weak offset π–π interactions [inter-centroid distance = 3.586 (1) Å], forming layers parallel to the ab plane.http://scripts.iucr.org/cgi-bin/paper?S2414314617004655crystal structurepyridinepyridiniumthiadiazolehydrogen bondingoffset π–π interactions |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Abdelhakim Laachir Fouad Bentiss Salaheddine Guesmi Mohamed Saadi Lahcen El Ammari |
| spellingShingle |
Abdelhakim Laachir Fouad Bentiss Salaheddine Guesmi Mohamed Saadi Lahcen El Ammari 2-[5-(Pyridin-2-yl)-1,3,4-thiadiazol-2-yl]pyridin-1-ium perchlorate IUCrData crystal structure pyridine pyridinium thiadiazole hydrogen bonding offset π–π interactions |
| author_facet |
Abdelhakim Laachir Fouad Bentiss Salaheddine Guesmi Mohamed Saadi Lahcen El Ammari |
| author_sort |
Abdelhakim Laachir |
| title |
2-[5-(Pyridin-2-yl)-1,3,4-thiadiazol-2-yl]pyridin-1-ium perchlorate |
| title_short |
2-[5-(Pyridin-2-yl)-1,3,4-thiadiazol-2-yl]pyridin-1-ium perchlorate |
| title_full |
2-[5-(Pyridin-2-yl)-1,3,4-thiadiazol-2-yl]pyridin-1-ium perchlorate |
| title_fullStr |
2-[5-(Pyridin-2-yl)-1,3,4-thiadiazol-2-yl]pyridin-1-ium perchlorate |
| title_full_unstemmed |
2-[5-(Pyridin-2-yl)-1,3,4-thiadiazol-2-yl]pyridin-1-ium perchlorate |
| title_sort |
2-[5-(pyridin-2-yl)-1,3,4-thiadiazol-2-yl]pyridin-1-ium perchlorate |
| publisher |
International Union of Crystallography |
| series |
IUCrData |
| issn |
2414-3146 |
| publishDate |
2017-03-01 |
| description |
The cation of the title molecular salt, C12H9N4S+·ClO4−, is approximately planar, with the pyridine and pyridinium rings being inclined to the central thiadiazole ring by 6.51 (9) and 9.13 (9)°, respectively. The dihedral angle between the pyridine and pyridinium rings is 12.91 (10)°. In the crystal, the cations are linked by N—H...O and C—H...O hydrogen bonds, involving the perchlorate anion, forming chains propagating along the [100] direction. The chains are linked by weak offset π–π interactions [inter-centroid distance = 3.586 (1) Å], forming layers parallel to the ab plane. |
| topic |
crystal structure pyridine pyridinium thiadiazole hydrogen bonding offset π–π interactions |
| url |
http://scripts.iucr.org/cgi-bin/paper?S2414314617004655 |
| work_keys_str_mv |
AT abdelhakimlaachir 25pyridin2yl134thiadiazol2ylpyridin1iumperchlorate AT fouadbentiss 25pyridin2yl134thiadiazol2ylpyridin1iumperchlorate AT salaheddineguesmi 25pyridin2yl134thiadiazol2ylpyridin1iumperchlorate AT mohamedsaadi 25pyridin2yl134thiadiazol2ylpyridin1iumperchlorate AT lahcenelammari 25pyridin2yl134thiadiazol2ylpyridin1iumperchlorate |
| _version_ |
1725318475973394432 |