Selective coupling reaction between 2,6-diiodoanisoles and terminal alkynes catalyzed by Pd(PPh3)2Cl2 and CuI
<em>The cross-coupling reaction between aryl halides and terminal alkynes, catalyzed by palladium complexes and copper (I) salts, consists in an efficient synthetic tool for the formation of C-C bonds, resulting in disubstituted acetylenic compounds. Accordingly, in this work we present our pr...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Universidade Federal de Mato Grosso do Sul
2012-06-01
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| Series: | Orbital: The Electronic Journal of Chemistry |
| Subjects: | |
| Online Access: | http://orbital.ufms.br/index.php/Chemistry/article/view/363 |
| Summary: | <em>The cross-coupling reaction between aryl halides and terminal alkynes, catalyzed by palladium complexes and copper (I) salts, consists in an efficient synthetic tool for the formation of C-C bonds, resulting in disubstituted acetylenic compounds. Accordingly, in this work we present our preliminary results involving the selective cross-coupling reaction between 2,6-diiodoanisoles and terminal alkynes, catalyzed by Pd(PPh<sub>3</sub>)<sub>2</sub>Cl<sub>2</sub> and CuI, in the formation of 2-iodo-alkynylanisoles (scheme 1).</em> |
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| ISSN: | 1984-6428 |