Gas adsorption and desorption effects on cylinders and their importance for long-term gas records

It is well known that gases adsorb on many surfaces, in particular metal surfaces. There are two main forms responsible for these effects (i) physisorption and (ii) chemisorption. Physisorption is associated with lower binding energies in the order of 1–10 kJ mol<sup>−1</sup>, compared t...

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Bibliographic Details
Main Authors: M. C. Leuenberger, M. F. Schibig, P. Nyfeler
Format: Article
Language:English
Published: Copernicus Publications 2015-12-01
Series:Atmospheric Measurement Techniques
Online Access:http://www.atmos-meas-tech.net/8/5289/2015/amt-8-5289-2015.pdf