MoO₃ Nanobelts Embedded Polypyrrole/SIS Copolymer Blends for Improved Electro-Mechanical Dual Applications

• Main Authors: Arslan Umer, Faroha Liaqat, Azhar Mahmood
• Format: Article
• Language: English
• Published: MDPI AG 2020-02-01
• Series: Polymers
• Subjects: polypyrrole; poly(styrene-isoprene-styrene); nanobelts; conductivity; tensile testing
• Online Access: https://www.mdpi.com/2073-4360/12/2/353

This research endeavor aimed to develop thin film blends of polypyrrole (PPy) and poly (styrene-isoprene-styrene) (SIS) with MoO₃ as a nanofiller for improved mechanical and electrical properties to widen its scope in the field of mechatronics. This study reports blends of polypyrrole (PPy) and poly (styrene-isoprene-styrene) (SIS) tri-block copolymer showing improved mechanical and electrical attributes while employing MoO₃ nanobelts as nanofillers that additionally improves the abovementioned properties in the ensuing nanocomposites. The synthesis of PPy/SIS blends and MoO₃/PPy/SIS nanocomposites was well corroborated with XRD, SEM, FTIR, and EDS analysis. Successful blending of PPy was yielded up to 15 <i>w</i>/<i>w</i>% PPy in SIS, as beyond this self-agglomeration of PPy was observed. The results showed a remarkable increase in the conductivity of insulating SIS copolymer from 1.5 &#215; 10^&#8722;6.1 to 0.343 Scm^&#8722;1 and tensile strength up to 8.5 MPa with the 15 <i>w</i>/<i>w</i>% PPy/SIS blend. A further enhancement of the properties was recorded by embedding MoO₃ nanobelts with varying concentrations of the nanofillers into 15 <i>w</i>/<i>w</i>% PPy/SIS blends. The mechanical strength of the polymeric nanocomposites was enhanced up to 11.4 MPa with an increase in conductivity up to 1.51 Scm^&#8722;1 for 3 <i>w</i>/<i>w</i>% MoO₃/PPy-SIS blends. The resultant product exhibited good potential for electro-mechanical dual applications.