Dimethyl(2-oxo-2-phenylethyl)sulfanium bromide

Dimethyl(2-oxo-2-phenylethyl)sulfanium bromide

Single crystals of the title compound, C10H13OS+·Br−, were obtained from ethyl acetate/ethyl ether after reaction of acetophenone with hydrobromic acid and dimethylsulfoxide. The carbonyl group is almost coplanar with the neighbouring phenyl ring [O—C&amp...

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Main Authors: Zhiling Cao, Fujun Yin, Weiwei Liu
Format: Article
Language:English
Published: International Union of Crystallography 2010-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810046404
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spelling doaj-4e57919b0bcf46e88057cbcd2a2914472020-11-24T22:09:36ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612o3197o319710.1107/S1600536810046404Dimethyl(2-oxo-2-phenylethyl)sulfanium bromideZhiling CaoFujun YinWeiwei LiuSingle crystals of the title compound, C10H13OS+·Br−, were obtained from ethyl acetate/ethyl ether after reaction of acetophenone with hydrobromic acid and dimethylsulfoxide. The carbonyl group is almost coplanar with the neighbouring phenyl ring [O—C—C—C = 178.9 (2)°]. The sulfanium group shows a trigonal–pyramidal geometry at the S atom. The crystal structure is stabilized by C—H...Br hydrogen-bonding interactions. Weak π–π interactions link adjacent phenyl rings [centroid–centroid distance = 3.946 (2) Å]. http://scripts.iucr.org/cgi-bin/paper?S1600536810046404
collection DOAJ
language English
format Article
sources DOAJ
author Zhiling Cao
Fujun Yin
Weiwei Liu
spellingShingle Zhiling Cao
Fujun Yin
Weiwei Liu
Dimethyl(2-oxo-2-phenylethyl)sulfanium bromide
Acta Crystallographica Section E
author_facet Zhiling Cao
Fujun Yin
Weiwei Liu
author_sort Zhiling Cao
title Dimethyl(2-oxo-2-phenylethyl)sulfanium bromide
title_short Dimethyl(2-oxo-2-phenylethyl)sulfanium bromide
title_full Dimethyl(2-oxo-2-phenylethyl)sulfanium bromide
title_fullStr Dimethyl(2-oxo-2-phenylethyl)sulfanium bromide
title_full_unstemmed Dimethyl(2-oxo-2-phenylethyl)sulfanium bromide
title_sort dimethyl(2-oxo-2-phenylethyl)sulfanium bromide
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-12-01
description Single crystals of the title compound, C10H13OS+·Br−, were obtained from ethyl acetate/ethyl ether after reaction of acetophenone with hydrobromic acid and dimethylsulfoxide. The carbonyl group is almost coplanar with the neighbouring phenyl ring [O—C—C—C = 178.9 (2)°]. The sulfanium group shows a trigonal–pyramidal geometry at the S atom. The crystal structure is stabilized by C—H...Br hydrogen-bonding interactions. Weak π–π interactions link adjacent phenyl rings [centroid–centroid distance = 3.946 (2) Å].
url http://scripts.iucr.org/cgi-bin/paper?S1600536810046404
work_keys_str_mv AT zhilingcao dimethyl2oxo2phenylethylsulfaniumbromide
AT fujunyin dimethyl2oxo2phenylethylsulfaniumbromide
AT weiweiliu dimethyl2oxo2phenylethylsulfaniumbromide
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