Densification of Ceramic Matrix Composite Preforms by Si<sub>2</sub>N<sub>2</sub>O Formed by Reaction of Si with SiO<sub>2</sub> under High Nitrogen Pressure. Part 2: Materials Properties

Ceramic matrix composites (CMCs) have been prepared and optimized as already described in part I of this paper. The fibrous preform made of Hi-Nicalon S fibers was densified by a matrix composed of Si<sub>2</sub>N<sub>2</sub>O prepared inside the CMC by reacting a mixture of...

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Bibliographic Details
Main Authors: Brice Taillet, René Pailler, Francis Teyssandier
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Journal of Composites Science
Subjects:
Online Access:https://www.mdpi.com/2504-477X/5/7/179
Description
Summary:Ceramic matrix composites (CMCs) have been prepared and optimized as already described in part I of this paper. The fibrous preform made of Hi-Nicalon S fibers was densified by a matrix composed of Si<sub>2</sub>N<sub>2</sub>O prepared inside the CMC by reacting a mixture of Si and SiO<sub>2</sub> under high nitrogen pressure. This part describes the oxidation resistance and mechanical properties of the optimized CMC. The CMC submitted to oxidation in wet oxygen at 1400 °C for 170 h exhibited an oxidation gradient from the surface to almost the center of the sample. In the outer part of the sample, Si<sub>2</sub>N<sub>2</sub>O, Si<sub>3</sub>N<sub>4</sub> and SiC were oxidized into silica in the cristobalite-crystallized form. The matrix microstructure looks similar to the original one at the center of the sample, while at the surface large pores are observed and the fiber/matrix interphase is consumed by oxidation. The elastic modulus and the hardness measured at room temperature by nano-indentation are, respectively, 100 and 8 GPa. The elastic modulus measured at room temperature by tensile tests ranges from 150 to 160 GPa and the ultimate yield strength from 320 to 390 MPa, which corresponds to a yield strain of about 0.6%. The yield strength identified by acoustic emission is about 40 MPa.
ISSN:2504-477X