Ring Expansion of Alkylidenecarbenes Derived from Lactams, Lactones, and Thiolactones into Strained Heterocyclic Alkynes: A Theoretical Study

Ring Expansion of Alkylidenecarbenes Derived from Lactams, Lactones, and Thiolactones into Strained Heterocyclic Alkynes: A Theoretical Study

Strained cycloalkynes are of considerable interest to theoreticians and experimentalists, and possess much synthetic value as well. Herein, a series of cyclic alkylidenecarbenes—formally obtained by replacing the carbonyl oxygen of four-, five-, and six-membered lactams, lactones, and thio...

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Bibliographic Details
Main Authors: Nguyen Nhat Thu Le, Josefine Just, Jonathan M. Pankauski, Paul R. Rablen, Dasan M. Thamattoor
Format: Article
Language:English
Published: MDPI AG 2019-02-01
Series:Molecules
Subjects:
alkylidenecarbenes
rearrangements
strained cycloalkynes
calculations
Online Access:https://www.mdpi.com/1420-3049/24/3/593

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