Preparation of Nitrogen-Doped Carbon Material from Monosodium Glutamate and Its Catalytic Performance
N-doped carbon materials (NCMs) are generally used as electrode materials, and seldom used as catalysts in chemical reaction. In this work, NCMs were prepared by high-temperature pyrolysis using monosodium glutamate as sources of both carbon and nitrogen, magnesium acetate as a porogen, and nickel h...
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Diponegoro University
2019-04-01
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| Series: | Bulletin of Chemical Reaction Engineering & Catalysis |
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| Online Access: | https://ejournal2.undip.ac.id/index.php/bcrec/article/view/2377 |
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doaj-4da11b01b7d14ab1891e325a6db084902021-05-02T00:47:07ZengDiponegoro UniversityBulletin of Chemical Reaction Engineering & Catalysis1978-29932019-04-01141283410.9767/bcrec.14.1.2377.28-341654Preparation of Nitrogen-Doped Carbon Material from Monosodium Glutamate and Its Catalytic PerformanceYing Mei Zhou0Xiao Hui Wang1Ke Ying Cai2Ji Ming Wu3Peng Wang4Ming Song5School of Chemistry and Chemical Engineering, Xuzhou University of Technology , Xuzhou, Jiangsu 221018, ChinaSchool of Chemistry and Chemical Engineering, Xuzhou University of Technology , Xuzhou, Jiangsu 221018, ChinaSchool of Chemistry and Chemical Engineering, Xuzhou University of Technology , Xuzhou, Jiangsu 221018, ChinaSchool of Chemistry and Chemical Engineering, Xuzhou University of Technology , Xuzhou, Jiangsu 221018, ChinaSchool of Chemistry and Chemical Engineering, Xuzhou University of Technology , Xuzhou, Jiangsu 221018, ChinaSchool of Chemistry and Chemical Engineering, Xuzhou University of Technology , Xuzhou, Jiangsu 221018, ChinaN-doped carbon materials (NCMs) are generally used as electrode materials, and seldom used as catalysts in chemical reaction. In this work, NCMs were prepared by high-temperature pyrolysis using monosodium glutamate as sources of both carbon and nitrogen, magnesium acetate as a porogen, and nickel hydroxide as a graphitization catalyst. The catalytic performance of NCMs was investigated in the reduction of 4-nitrophenol (4-NP) with potassium borohydride at 30 ºC. As metal-free catalysts, all of the NCMs can catalyze the reaction. The graphitization degree and N-doped amount of NCM have a great influence on the catalytic activity. The NCM annealed at 800 ºC has higher activity and stability. The reaction rate constant can reach 0.57 min-1, and the activation energy was about 36.4 kJ/mol. Copyright © 2019 BCREC Group. All rights reservedhttps://ejournal2.undip.ac.id/index.php/bcrec/article/view/2377monosodium glutamatenitrogen-doped carbon materialreduction4-nitrophenolmetal-free catalyst |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Ying Mei Zhou Xiao Hui Wang Ke Ying Cai Ji Ming Wu Peng Wang Ming Song |
| spellingShingle |
Ying Mei Zhou Xiao Hui Wang Ke Ying Cai Ji Ming Wu Peng Wang Ming Song Preparation of Nitrogen-Doped Carbon Material from Monosodium Glutamate and Its Catalytic Performance Bulletin of Chemical Reaction Engineering & Catalysis monosodium glutamate nitrogen-doped carbon material reduction 4-nitrophenol metal-free catalyst |
| author_facet |
Ying Mei Zhou Xiao Hui Wang Ke Ying Cai Ji Ming Wu Peng Wang Ming Song |
| author_sort |
Ying Mei Zhou |
| title |
Preparation of Nitrogen-Doped Carbon Material from Monosodium Glutamate and Its Catalytic Performance |
| title_short |
Preparation of Nitrogen-Doped Carbon Material from Monosodium Glutamate and Its Catalytic Performance |
| title_full |
Preparation of Nitrogen-Doped Carbon Material from Monosodium Glutamate and Its Catalytic Performance |
| title_fullStr |
Preparation of Nitrogen-Doped Carbon Material from Monosodium Glutamate and Its Catalytic Performance |
| title_full_unstemmed |
Preparation of Nitrogen-Doped Carbon Material from Monosodium Glutamate and Its Catalytic Performance |
| title_sort |
preparation of nitrogen-doped carbon material from monosodium glutamate and its catalytic performance |
| publisher |
Diponegoro University |
| series |
Bulletin of Chemical Reaction Engineering & Catalysis |
| issn |
1978-2993 |
| publishDate |
2019-04-01 |
| description |
N-doped carbon materials (NCMs) are generally used as electrode materials, and seldom used as catalysts in chemical reaction. In this work, NCMs were prepared by high-temperature pyrolysis using monosodium glutamate as sources of both carbon and nitrogen, magnesium acetate as a porogen, and nickel hydroxide as a graphitization catalyst. The catalytic performance of NCMs was investigated in the reduction of 4-nitrophenol (4-NP) with potassium borohydride at 30 ºC. As metal-free catalysts, all of the NCMs can catalyze the reaction. The graphitization degree and N-doped amount of NCM have a great influence on the catalytic activity. The NCM annealed at 800 ºC has higher activity and stability. The reaction rate constant can reach 0.57 min-1, and the activation energy was about 36.4 kJ/mol. Copyright © 2019 BCREC Group. All rights reserved |
| topic |
monosodium glutamate nitrogen-doped carbon material reduction 4-nitrophenol metal-free catalyst |
| url |
https://ejournal2.undip.ac.id/index.php/bcrec/article/view/2377 |
| work_keys_str_mv |
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