LaCoO3 perovskite-type catalysts in syngas conversion

LaCoO3 samples were obtained by the hydrothermal and citrate methods. The dynamics of the phase transformations of the initial hydroxo compounds into the oxide state and the subsequent reduction in a hydrogen-containing mixture were studied by the differential thermal analysis and X-ray diffraction...

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Main Authors: Jetpisbayeva Gulim Danebaevna, Dokuchits Eugene Vladimirovich, Tafilevich Angelina Nikolaevna, Minyukova Tatyana Petrovna, Massalimova Bakytgul Kabykenovna, Sadykov Vladislav Aleksandrovich
Format: Article
Language:English
Published: De Gruyter 2020-05-01
Series:Open Chemistry
Subjects:
Online Access:https://doi.org/10.1515/chem-2020-0099
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spelling doaj-4d814989048c41d881ec31737c00d81f2021-09-06T19:19:37ZengDe GruyterOpen Chemistry2391-54202020-05-0118148248710.1515/chem-2020-0099chem-2020-0099LaCoO3 perovskite-type catalysts in syngas conversionJetpisbayeva Gulim Danebaevna0Dokuchits Eugene Vladimirovich1Tafilevich Angelina Nikolaevna2Minyukova Tatyana Petrovna3Massalimova Bakytgul Kabykenovna4Sadykov Vladislav Aleksandrovich5Department of Chemistry and Chemical Technology, Taraz State University, 60, st. Tole Bi, 080000, Taraz, KazakhstanDepartment of Physical Chemistry, Novosibirsk State University, 2, Pirogova St., 630090, Novosibirsk, RussiaDepartment of Physical Chemistry, Novosibirsk State University, 2, Pirogova St., 630090, Novosibirsk, RussiaDepartment of Physical Chemistry, Novosibirsk State University, 2, Pirogova St., 630090, Novosibirsk, RussiaDepartment of Chemistry and Chemical Technology, Taraz State University, 60, st. Tole Bi, 080000, Taraz, KazakhstanDepartment of Physical Chemistry, Novosibirsk State University, 2, Pirogova St., 630090, Novosibirsk, RussiaLaCoO3 samples were obtained by the hydrothermal and citrate methods. The dynamics of the phase transformations of the initial hydroxo compounds into the oxide state and the subsequent reduction in a hydrogen-containing mixture were studied by the differential thermal analysis and X-ray diffraction methods. The results of the catalytic tests in the syngas conversion showed that the path of conversion depends on the phase composition of the catalyst in the oxide state. In contrast to the standard CoAl sample, alcohols prevail in the liquid products formed on LaCoO3 catalysts.https://doi.org/10.1515/chem-2020-0099synthesis gas transformationsynthesis of alcohols
collection DOAJ
language English
format Article
sources DOAJ
author Jetpisbayeva Gulim Danebaevna
Dokuchits Eugene Vladimirovich
Tafilevich Angelina Nikolaevna
Minyukova Tatyana Petrovna
Massalimova Bakytgul Kabykenovna
Sadykov Vladislav Aleksandrovich
spellingShingle Jetpisbayeva Gulim Danebaevna
Dokuchits Eugene Vladimirovich
Tafilevich Angelina Nikolaevna
Minyukova Tatyana Petrovna
Massalimova Bakytgul Kabykenovna
Sadykov Vladislav Aleksandrovich
LaCoO3 perovskite-type catalysts in syngas conversion
Open Chemistry
synthesis gas transformation
synthesis of alcohols
author_facet Jetpisbayeva Gulim Danebaevna
Dokuchits Eugene Vladimirovich
Tafilevich Angelina Nikolaevna
Minyukova Tatyana Petrovna
Massalimova Bakytgul Kabykenovna
Sadykov Vladislav Aleksandrovich
author_sort Jetpisbayeva Gulim Danebaevna
title LaCoO3 perovskite-type catalysts in syngas conversion
title_short LaCoO3 perovskite-type catalysts in syngas conversion
title_full LaCoO3 perovskite-type catalysts in syngas conversion
title_fullStr LaCoO3 perovskite-type catalysts in syngas conversion
title_full_unstemmed LaCoO3 perovskite-type catalysts in syngas conversion
title_sort lacoo3 perovskite-type catalysts in syngas conversion
publisher De Gruyter
series Open Chemistry
issn 2391-5420
publishDate 2020-05-01
description LaCoO3 samples were obtained by the hydrothermal and citrate methods. The dynamics of the phase transformations of the initial hydroxo compounds into the oxide state and the subsequent reduction in a hydrogen-containing mixture were studied by the differential thermal analysis and X-ray diffraction methods. The results of the catalytic tests in the syngas conversion showed that the path of conversion depends on the phase composition of the catalyst in the oxide state. In contrast to the standard CoAl sample, alcohols prevail in the liquid products formed on LaCoO3 catalysts.
topic synthesis gas transformation
synthesis of alcohols
url https://doi.org/10.1515/chem-2020-0099
work_keys_str_mv AT jetpisbayevagulimdanebaevna lacoo3perovskitetypecatalystsinsyngasconversion
AT dokuchitseugenevladimirovich lacoo3perovskitetypecatalystsinsyngasconversion
AT tafilevichangelinanikolaevna lacoo3perovskitetypecatalystsinsyngasconversion
AT minyukovatatyanapetrovna lacoo3perovskitetypecatalystsinsyngasconversion
AT massalimovabakytgulkabykenovna lacoo3perovskitetypecatalystsinsyngasconversion
AT sadykovvladislavaleksandrovich lacoo3perovskitetypecatalystsinsyngasconversion
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