7-Bromo-2-methyl-1-(phenylsulfonyl)naphtho[2,1-b]furan
The title compound, C19H13BrO3S, was prepared by the oxidation of 7-bromo-2-methyl-1-(phenylsulfanyl)naphtho[2,1-b]furan with 3-chloroperoxybenzoic acid. The phenyl ring makes a dihedral angle of 80.4 (2)° with the plane of the naphthofuran fragment. The crystal structure is stabi...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680801177X |
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doaj-4d0ef8c89e1348b48fbdfcfb34c2a5e92020-11-25T00:50:38ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-05-01645o944o94410.1107/S160053680801177X7-Bromo-2-methyl-1-(phenylsulfonyl)naphtho[2,1-b]furanUk LeeByeng Wha SonPil Ja SeoHong Dae ChoiThe title compound, C19H13BrO3S, was prepared by the oxidation of 7-bromo-2-methyl-1-(phenylsulfanyl)naphtho[2,1-b]furan with 3-chloroperoxybenzoic acid. The phenyl ring makes a dihedral angle of 80.4 (2)° with the plane of the naphthofuran fragment. The crystal structure is stabilized by aromatic π–π stacking interactions between the brominated benzene ring and the central benzene ring of the naphthofuran system of neighbouring molecules; the centroid–centroid distances within the stack are 3.889 (3) and 3.981 (3) Å. In addition, the stacked molecules exhibit C—H...π, inter- and intramolecular C—H...O interactions.http://scripts.iucr.org/cgi-bin/paper?S160053680801177X |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Uk Lee Byeng Wha Son Pil Ja Seo Hong Dae Choi |
| spellingShingle |
Uk Lee Byeng Wha Son Pil Ja Seo Hong Dae Choi 7-Bromo-2-methyl-1-(phenylsulfonyl)naphtho[2,1-b]furan Acta Crystallographica Section E |
| author_facet |
Uk Lee Byeng Wha Son Pil Ja Seo Hong Dae Choi |
| author_sort |
Uk Lee |
| title |
7-Bromo-2-methyl-1-(phenylsulfonyl)naphtho[2,1-b]furan |
| title_short |
7-Bromo-2-methyl-1-(phenylsulfonyl)naphtho[2,1-b]furan |
| title_full |
7-Bromo-2-methyl-1-(phenylsulfonyl)naphtho[2,1-b]furan |
| title_fullStr |
7-Bromo-2-methyl-1-(phenylsulfonyl)naphtho[2,1-b]furan |
| title_full_unstemmed |
7-Bromo-2-methyl-1-(phenylsulfonyl)naphtho[2,1-b]furan |
| title_sort |
7-bromo-2-methyl-1-(phenylsulfonyl)naphtho[2,1-b]furan |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2008-05-01 |
| description |
The title compound, C19H13BrO3S, was prepared by the oxidation of 7-bromo-2-methyl-1-(phenylsulfanyl)naphtho[2,1-b]furan with 3-chloroperoxybenzoic acid. The phenyl ring makes a dihedral angle of 80.4 (2)° with the plane of the naphthofuran fragment. The crystal structure is stabilized by aromatic π–π stacking interactions between the brominated benzene ring and the central benzene ring of the naphthofuran system of neighbouring molecules; the centroid–centroid distances within the stack are 3.889 (3) and 3.981 (3) Å. In addition, the stacked molecules exhibit C—H...π, inter- and intramolecular C—H...O interactions. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S160053680801177X |
| work_keys_str_mv |
AT uklee 7bromo2methyl1phenylsulfonylnaphtho21bfuran AT byengwhason 7bromo2methyl1phenylsulfonylnaphtho21bfuran AT piljaseo 7bromo2methyl1phenylsulfonylnaphtho21bfuran AT hongdaechoi 7bromo2methyl1phenylsulfonylnaphtho21bfuran |
| _version_ |
1725247360037027840 |