Crystal structure and absolute configuration of (3aS,4S,5R,7aR)-2,2,7-trimethyl-3a,4,5,7a-tetrahydro-1,3-benzodioxole-4,5-diol

Crystal structure and absolute configuration of (3aS,4S,5R,7aR)-2,2,7-trimethyl-3a,4,5,7a-tetrahydro-1,3-benzodioxole-4,5-diol

The absolute configuration of the title compound, C10H16O4, determined as 3aS,4S,5R,7aR on the basis of the synthetic pathway, was confirmed by X-ray diffraction. The molecule contains a five- and a six-membered ring that adopt twisted and envelope conformations, respectively. The dihedral angle bet...

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Bibliographic Details
Main Authors: Mario A. Macías, Leopoldo Suescun, Enrique Pandolfi, Valeria Schapiro, Gaurao D. Tibhe, Álvaro W. Mombrú
Format: Article
Language:English
Published: International Union of Crystallography 2015-09-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
epoxycyclohexenones
absolute configuration
chiral crystal
chemoenzymatic strategy
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015014590

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http://scripts.iucr.org/cgi-bin/paper?S2056989015014590

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