(Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ2S4,S5)tin(IV)
The Sn atom in the title compound, [Sn(C6H5)2(C3S5)(C2H6OS)], exists within a distorted trigonal-bipyramidal geometry defined by two S atoms of the 1,2-dithiole-3-thione-4,5-dithiolate dianion, two ipso-C atoms from the phenyl groups, and the O atom of the dimethyl sulfoxide molecule. In this descri...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809047904 |
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doaj-4cb7da6f92284464af92024291cdb6aa2020-11-24T21:25:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1592m159310.1107/S1600536809047904(Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ2S4,S5)tin(IV)James L. WardellEdward R. T. TiekinkNadia M. ComerlatoSolange M. S. V. WardellThe Sn atom in the title compound, [Sn(C6H5)2(C3S5)(C2H6OS)], exists within a distorted trigonal-bipyramidal geometry defined by two S atoms of the 1,2-dithiole-3-thione-4,5-dithiolate dianion, two ipso-C atoms from the phenyl groups, and the O atom of the dimethyl sulfoxide molecule. In this description, one of the S atoms and the O occupy axial positions. In the crystal, centrosymmetrically related molecules associate via pairs of C—H...S contacts, forming dimeric aggregates. http://scripts.iucr.org/cgi-bin/paper?S1600536809047904 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
James L. Wardell Edward R. T. Tiekink Nadia M. Comerlato Solange M. S. V. Wardell |
| spellingShingle |
James L. Wardell Edward R. T. Tiekink Nadia M. Comerlato Solange M. S. V. Wardell (Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ2S4,S5)tin(IV) Acta Crystallographica Section E |
| author_facet |
James L. Wardell Edward R. T. Tiekink Nadia M. Comerlato Solange M. S. V. Wardell |
| author_sort |
James L. Wardell |
| title |
(Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ2S4,S5)tin(IV) |
| title_short |
(Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ2S4,S5)tin(IV) |
| title_full |
(Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ2S4,S5)tin(IV) |
| title_fullStr |
(Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ2S4,S5)tin(IV) |
| title_full_unstemmed |
(Dimethyl sulfoxide-κO)diphenyl(3-thioxo-3H-1,2-dithiole-4,5-dithiolato-κ2S4,S5)tin(IV) |
| title_sort |
(dimethyl sulfoxide-κo)diphenyl(3-thioxo-3h-1,2-dithiole-4,5-dithiolato-κ2s4,s5)tin(iv) |
| publisher |
International Union of Crystallography |
| series |
Acta Crystallographica Section E |
| issn |
1600-5368 |
| publishDate |
2009-12-01 |
| description |
The Sn atom in the title compound, [Sn(C6H5)2(C3S5)(C2H6OS)], exists within a distorted trigonal-bipyramidal geometry defined by two S atoms of the 1,2-dithiole-3-thione-4,5-dithiolate dianion, two ipso-C atoms from the phenyl groups, and the O atom of the dimethyl sulfoxide molecule. In this description, one of the S atoms and the O occupy axial positions. In the crystal, centrosymmetrically related molecules associate via pairs of C—H...S contacts, forming dimeric aggregates. |
| url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809047904 |
| work_keys_str_mv |
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