The airborne mass spectrometer AIMS – Part 1: AIMS-H₂O for UTLS water vapor measurements

• Main Authors: S. Kaufmann, C. Voigt, T. Jurkat, T. Thornberry, D. W. Fahey, R.-S. Gao, R. Schlage, D. Schäuble, M. Zöger
• Format: Article
• Language: English
• Published: Copernicus Publications 2016-03-01
• Series: Atmospheric Measurement Techniques
• Online Access: http://www.atmos-meas-tech.net/9/939/2016/amt-9-939-2016.pdf
• ISSN: 1867-1381; 1867-8548

In the upper troposphere and lower stratosphere (UTLS), the accurate quantification of low water vapor concentrations has presented a significant measurement challenge. The instrumental uncertainties are passed on to estimates of H₂O transport, cloud formation and the role of H₂O in the UTLS energy budget and resulting effects on surface temperatures. To address the uncertainty in UTLS H₂O determination, the airborne mass spectrometer AIMS-H₂O, with in-flight calibration, has been developed for fast and accurate airborne water vapor measurements. <br><br> We present a new setup to measure water vapor by direct ionization of ambient air. Air is sampled via a backward facing inlet that includes a bypass flow to assure short residence times (&lt; 0.2 s) in the inlet line, which allows the instrument to achieve a time resolution of  ∼ 4 Hz, limited by the sampling frequency of the mass spectrometer. From the main inlet flow, a smaller flow is extracted into the novel pressure-controlled gas discharge ion source of the mass spectrometer. The air is directed through the gas discharge region where ion–molecule reactions lead to the production of hydronium ion clusters, H₃O⁺(H₂O)_<i>n</i> (<i>n</i> = 0, 1, 2), in a complex reaction scheme similar to the reactions in the D-region of the ionosphere. These ions are counted to quantify the ambient water vapor mixing ratio. The instrument is calibrated during flight using a new calibration source based on the catalytic reaction of H₂ and O₂ on a Pt surface to generate a calibration standard with well-defined and stable H₂O mixing ratios. In order to increase data quality over a range of mixing ratios, two data evaluation methods are presented for lower and higher H₂O mixing ratios respectively, using either only the H₃O⁺(H₂O) ions or the ratio of all water vapor dependent ions to the total ion current. Altogether, a range of water vapor mixing ratios from 1 to 500 parts per million by volume (ppmv) can be covered with an accuracy between 7 and 15 %. AIMS-H₂O was deployed on two DLR research aircraft, the Falcon during CONCERT (CONtrail and Cirrus ExpeRimenT) in 2011, and HALO during ML-CIRRUS (Mid-Latitude CIRRUS) in 2014. The comparison of AIMS-H₂O with the SHARC tunable diode laser hygrometer during ML-CIRRUS shows a correlation near to 1 in the range between 10 and 500 ppmv for the entire campaign.