4,7-Diaza-1-azoniacyclononane bromide

4,7-Diaza-1-azoniacyclononane bromide

The title compound, C6H16N3+·Br−, is the bromide of the monoprotonated azamacrocyclic triamine 1,4,7-triazacyclononane (tacn). The threefold axis of the triamine is broken by the protonation of one of the three amine functions. The ammonium proton is bonded in an intramole...

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Bibliographic Details
Main Authors: Thorsten Allscher, Peter Klüfers, Christine Neumann
Format: Article
Language:English
Published: International Union of Crystallography 2009-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809024313
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spelling doaj-4c390ec648fa4f8eba0c19de835b4be52020-11-25T00:17:36ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658o1734o173410.1107/S16005368090243134,7-Diaza-1-azoniacyclononane bromideThorsten AllscherPeter KlüfersChristine NeumannThe title compound, C6H16N3+·Br−, is the bromide of the monoprotonated azamacrocyclic triamine 1,4,7-triazacyclononane (tacn). The threefold axis of the triamine is broken by the protonation of one of the three amine functions. The ammonium proton is bonded in an intramolecular symmetrically bifurcated hydrogen bond to the two endodentate amine functions. Direct cation–anion contacts are established via N—H...Br hydrogen bonds between the bromide anions and tacnH+ cations. http://scripts.iucr.org/cgi-bin/paper?S1600536809024313
collection DOAJ
language English
format Article
sources DOAJ
author Thorsten Allscher
Peter Klüfers
Christine Neumann
spellingShingle Thorsten Allscher
Peter Klüfers
Christine Neumann
4,7-Diaza-1-azoniacyclononane bromide
Acta Crystallographica Section E
author_facet Thorsten Allscher
Peter Klüfers
Christine Neumann
author_sort Thorsten Allscher
title 4,7-Diaza-1-azoniacyclononane bromide
title_short 4,7-Diaza-1-azoniacyclononane bromide
title_full 4,7-Diaza-1-azoniacyclononane bromide
title_fullStr 4,7-Diaza-1-azoniacyclononane bromide
title_full_unstemmed 4,7-Diaza-1-azoniacyclononane bromide
title_sort 4,7-diaza-1-azoniacyclononane bromide
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-08-01
description The title compound, C6H16N3+·Br−, is the bromide of the monoprotonated azamacrocyclic triamine 1,4,7-triazacyclononane (tacn). The threefold axis of the triamine is broken by the protonation of one of the three amine functions. The ammonium proton is bonded in an intramolecular symmetrically bifurcated hydrogen bond to the two endodentate amine functions. Direct cation–anion contacts are established via N—H...Br hydrogen bonds between the bromide anions and tacnH+ cations.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809024313
work_keys_str_mv AT thorstenallscher 47diaza1azoniacyclononanebromide
AT peterklamp252fers 47diaza1azoniacyclononanebromide
AT christineneumann 47diaza1azoniacyclononanebromide
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