Terbium(III) hydrogendiphosphate(V) tetrahydrate
The Tb atom of the title compound, TbHP2O7·4H2O, is coordinated by the O atoms of three symmetrically independent water molecules and by five O atoms belonging to HP2O7− groups. The TbO8 polyhedra are interconnected by the diphospate anions, forming a three-dimensional network whi...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808001992 |
| Summary: | The Tb atom of the title compound, TbHP2O7·4H2O, is coordinated by the O atoms of three symmetrically independent water molecules and by five O atoms belonging to HP2O7− groups. The TbO8 polyhedra are interconnected by the diphospate anions, forming a three-dimensional network which is additionally stabilized by O—H...O hydrogen bonding between water molecules and O atoms of the HP2O7− anions. Uncoordinated water molecules are situated in channels and are connected via hydrogen bonds with the framework. |
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| ISSN: | 1600-5368 |