Towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworks

Porous framework material DUT-49 was recently demonstrated to exhibit a unique counterintuitive negative gas adsorption (NGA) behaviour. Here the authors identify framework DUT-50 as an additional pressure amplifying material that features distinct NGA transitions, and suggest structural design crit...

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Main Authors: Simon Krause, Jack D. Evans, Volodymyr Bon, Irena Senkovska, Paul Iacomi, Felicitas Kolbe, Sebastian Ehrling, Erik Troschke, Jürgen Getzschmann, Daniel M. Többens, Alexandra Franz, Dirk Wallacher, Pascal G. Yot, Guillaume Maurin, Eike Brunner, Philip L. Llewellyn, François-Xavier Coudert, Stefan Kaskel
Format: Article
Language:English
Published: Nature Publishing Group 2019-08-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-019-11565-3
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spelling doaj-4b71785dd92042d49da977ef7e056c042021-05-11T11:52:09ZengNature Publishing GroupNature Communications2041-17232019-08-0110111210.1038/s41467-019-11565-3Towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworksSimon Krause0Jack D. Evans1Volodymyr Bon2Irena Senkovska3Paul Iacomi4Felicitas Kolbe5Sebastian Ehrling6Erik Troschke7Jürgen Getzschmann8Daniel M. Többens9Alexandra Franz10Dirk Wallacher11Pascal G. Yot12Guillaume Maurin13Eike Brunner14Philip L. Llewellyn15François-Xavier Coudert16Stefan Kaskel17Faculty of Chemistry and Food Chemistry, TU DresdenFaculty of Chemistry and Food Chemistry, TU DresdenFaculty of Chemistry and Food Chemistry, TU DresdenFaculty of Chemistry and Food Chemistry, TU DresdenAix-Marseille Univ., CNRS, MADIREL (UMR 7246)Faculty of Chemistry and Food Chemistry, TU DresdenFaculty of Chemistry and Food Chemistry, TU DresdenFaculty of Chemistry and Food Chemistry, TU DresdenFaculty of Chemistry and Food Chemistry, TU DresdenHelmholtz-Zentrum Berlin für Materialien und EnergieHelmholtz-Zentrum Berlin für Materialien und EnergieHelmholtz-Zentrum Berlin für Materialien und EnergieInstitut Charles Gerhardt Montpellier UMR 5253 Univ. Montpellier CNRS UM ENSCM, Université de Montpellier, Place Eugène BataillonInstitut Charles Gerhardt Montpellier UMR 5253 Univ. Montpellier CNRS UM ENSCM, Université de Montpellier, Place Eugène BataillonFaculty of Chemistry and Food Chemistry, TU DresdenAix-Marseille Univ., CNRS, MADIREL (UMR 7246)Chimie ParisTech, PSL University, CNRS, Institut de Recherche de Chimie, ParisFaculty of Chemistry and Food Chemistry, TU DresdenPorous framework material DUT-49 was recently demonstrated to exhibit a unique counterintuitive negative gas adsorption (NGA) behaviour. Here the authors identify framework DUT-50 as an additional pressure amplifying material that features distinct NGA transitions, and suggest structural design criteria to access other such materials.https://doi.org/10.1038/s41467-019-11565-3
collection DOAJ
language English
format Article
sources DOAJ
author Simon Krause
Jack D. Evans
Volodymyr Bon
Irena Senkovska
Paul Iacomi
Felicitas Kolbe
Sebastian Ehrling
Erik Troschke
Jürgen Getzschmann
Daniel M. Többens
Alexandra Franz
Dirk Wallacher
Pascal G. Yot
Guillaume Maurin
Eike Brunner
Philip L. Llewellyn
François-Xavier Coudert
Stefan Kaskel
spellingShingle Simon Krause
Jack D. Evans
Volodymyr Bon
Irena Senkovska
Paul Iacomi
Felicitas Kolbe
Sebastian Ehrling
Erik Troschke
Jürgen Getzschmann
Daniel M. Többens
Alexandra Franz
Dirk Wallacher
Pascal G. Yot
Guillaume Maurin
Eike Brunner
Philip L. Llewellyn
François-Xavier Coudert
Stefan Kaskel
Towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworks
Nature Communications
author_facet Simon Krause
Jack D. Evans
Volodymyr Bon
Irena Senkovska
Paul Iacomi
Felicitas Kolbe
Sebastian Ehrling
Erik Troschke
Jürgen Getzschmann
Daniel M. Többens
Alexandra Franz
Dirk Wallacher
Pascal G. Yot
Guillaume Maurin
Eike Brunner
Philip L. Llewellyn
François-Xavier Coudert
Stefan Kaskel
author_sort Simon Krause
title Towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworks
title_short Towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworks
title_full Towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworks
title_fullStr Towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworks
title_full_unstemmed Towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworks
title_sort towards general network architecture design criteria for negative gas adsorption transitions in ultraporous frameworks
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2019-08-01
description Porous framework material DUT-49 was recently demonstrated to exhibit a unique counterintuitive negative gas adsorption (NGA) behaviour. Here the authors identify framework DUT-50 as an additional pressure amplifying material that features distinct NGA transitions, and suggest structural design criteria to access other such materials.
url https://doi.org/10.1038/s41467-019-11565-3
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