Chlorido{(E)-1-[(2-methoxyphenyl)diazenyl]naphthalen-2-olato}palladium(II)

Chlorido{(E)-1-[(2-methoxyphenyl)diazenyl]naphthalen-2-olato}palladium(II)

In the title complex, [Pd(C17H13N2O2)Cl], the PdII atom is tetracoordinated by an N and two O atoms of an (E)-1-[(2-methoxyphenyl)diazenyl]naphthalen-2-olate ligand and by a Cl atom, and has a square-planar coordination. In the crystal, molecules are linked by pairs of C—H...Cl hydrogen bonds, formi...

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Bibliographic Details
Main Authors: Assia Mili, Souheyla Chetioui, Djamil-Azzeddine Rouag, Jean-Pierre Djukic, Corinne Bailly
Format: Article
Language:English
Published: International Union of Crystallography 2016-04-01
Series:IUCrData
Subjects:
crystal structure
azo
1-phenylazo-2-naphthol
palladium(II)
C—H...Cl hydrogen bonds
π–π interactions
Online Access:http://scripts.iucr.org/cgi-bin/paper?S241431461600691X
Description
Summary:In the title complex, [Pd(C17H13N2O2)Cl], the PdII atom is tetracoordinated by an N and two O atoms of an (E)-1-[(2-methoxyphenyl)diazenyl]naphthalen-2-olate ligand and by a Cl atom, and has a square-planar coordination. In the crystal, molecules are linked by pairs of C—H...Cl hydrogen bonds, forming inversion dimers. The dimers are linked via offset π–π interactions [intercentroid distance = 3.546 (3) Å], forming chains running parallel to [100].
ISSN:2414-3146

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