Crystal structure of the lead-containing organic–inorganic hybrid: (C18H26N2)3[Pb4I14(DMSO)2]·2DMSO

Crystal structure of the lead-containing organic–inorganic hybrid: (C18H26N2)3[Pb4I14(DMSO)2]·2DMSO

The title compound, tris(1,1′-dibutyl-4,4′-bipyridine-1,1′-diium) bis(dimethyl sulfoxide)di-μ3-iodido-tetra-μ2-iodido-octaiodidotetralead(II) dimethyl sulfoxide disolvate, (C18H26N2)3[Pb4I14(C2H6OS)2]·2C2H6OS, belongs to a class of organic–inorganic hybrid materials with novel functionalities. In th...

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Bibliographic Details
Main Authors: Li Li, Dan Zhao, Zhi Liu, Dingchao Zhang, Zhenhao Hu, Kunlun Li, Jing Yang
Format: Article
Language:English
Published: International Union of Crystallography 2018-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
organic-inorganic hybrid
crystal structure
hydrogen-bonding interactions
π–π interactions
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018016584
Description
Summary:The title compound, tris(1,1′-dibutyl-4,4′-bipyridine-1,1′-diium) bis(dimethyl sulfoxide)di-μ3-iodido-tetra-μ2-iodido-octaiodidotetralead(II) dimethyl sulfoxide disolvate, (C18H26N2)3[Pb4I14(C2H6OS)2]·2C2H6OS, belongs to a class of organic–inorganic hybrid materials with novel functionalities. In this compound, C—H...O and C—H...I hydrogen-bonding interactions, π–π interactions, other short contacts and Pb octahedral chains are present, extending the crystal structure into a three-dimensional supramolecular network.
ISSN:2056-9890

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