Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate

Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate

In the crystal structure of the title compound, (C12H9N2)2[ZnCl4]·H2O, the two independent 1,10-phenanthrolinium cations are bridged by the water molecule and the tetrahedral tetrachloridozincate anion via N—H...O, O—H...Cl and N—H...Cl hydrogen bonds, forming chains along [100]. The chains are link...

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Main Authors: E. Govindan, Subramani Thirumurugan, Ayyakannu Sundaram Ganeshraja, Krishnamoorthy Anbalagan, A. SubbiahPandi
Format: Article
Language:English
Published: International Union of Crystallography 2014-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536814000208
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spelling doaj-4a10ef13495341aeb3989b1fd3b4b38d2020-11-24T21:28:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-02-01702m53m5310.1107/S1600536814000208su2681Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrateE. Govindan0Subramani Thirumurugan1Ayyakannu Sundaram Ganeshraja2Krishnamoorthy Anbalagan3A. SubbiahPandi4Department of Physics, Presidency College (Autonomous), Chennai 600 005, IndiaDepartment of Chemistry, Pondicherry University, Pondicherry 605 014, IndiaDepartment of Chemistry, Pondicherry University, Pondicherry 605 014, IndiaDepartment of Chemistry, Pondicherry University, Pondicherry 605 014, IndiaDepartment of Physics, Presidency College (Autonomous), Chennai 600 005, IndiaIn the crystal structure of the title compound, (C12H9N2)2[ZnCl4]·H2O, the two independent 1,10-phenanthrolinium cations are bridged by the water molecule and the tetrahedral tetrachloridozincate anion via N—H...O, O—H...Cl and N—H...Cl hydrogen bonds, forming chains along [100]. The chains are linked via C—H...Cl hydrogen bonds and a number of π–π interactions [centroid–centroid distances vary from 3.5594 (14) to 3.7057 (13) Å], forming a three-dimensional network. In each 1,10-phenanthrolinium cation, there is a short N—H...N interaction.http://scripts.iucr.org/cgi-bin/paper?S1600536814000208
collection DOAJ
language English
format Article
sources DOAJ
author E. Govindan
Subramani Thirumurugan
Ayyakannu Sundaram Ganeshraja
Krishnamoorthy Anbalagan
A. SubbiahPandi
spellingShingle E. Govindan
Subramani Thirumurugan
Ayyakannu Sundaram Ganeshraja
Krishnamoorthy Anbalagan
A. SubbiahPandi
Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate
Acta Crystallographica Section E
author_facet E. Govindan
Subramani Thirumurugan
Ayyakannu Sundaram Ganeshraja
Krishnamoorthy Anbalagan
A. SubbiahPandi
author_sort E. Govindan
title Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate
title_short Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate
title_full Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate
title_fullStr Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate
title_full_unstemmed Bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate
title_sort bis(1,10-phenanthrolin-1-ium) tetrachloridozincate monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2014-02-01
description In the crystal structure of the title compound, (C12H9N2)2[ZnCl4]·H2O, the two independent 1,10-phenanthrolinium cations are bridged by the water molecule and the tetrahedral tetrachloridozincate anion via N—H...O, O—H...Cl and N—H...Cl hydrogen bonds, forming chains along [100]. The chains are linked via C—H...Cl hydrogen bonds and a number of π–π interactions [centroid–centroid distances vary from 3.5594 (14) to 3.7057 (13) Å], forming a three-dimensional network. In each 1,10-phenanthrolinium cation, there is a short N—H...N interaction.
url http://scripts.iucr.org/cgi-bin/paper?S1600536814000208
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AT ayyakannusundaramganeshraja bis110phenanthrolin1iumtetrachloridozincatemonohydrate
AT krishnamoorthyanbalagan bis110phenanthrolin1iumtetrachloridozincatemonohydrate
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