Influence of fly ash on the pore structure of mortar using a differential scanning calorimetry analysis

• Main Authors: Rusin Zbigniew, Stępień Piotr, Skowera Karol
• Format: Article
• Language: English
• Published: EDP Sciences 2020-01-01
• Series: MATEC Web of Conferences
• Online Access: https://www.matec-conferences.org/articles/matecconf/pdf/2020/18/matecconf_matbud2020_01027.pdf

In the paper a low-temperature thermoporometry using differential scanning calorimetry (DSC) was employed for analyse of influence of siliceous fly ash (FA) on pore structure of non-air-entrained mortars (pore size, connectivity). A method of interpreting a heat flux differential scanning calorimetry records in pore structure was used for this purpose. The results demonstrated that the: (i) fly ash mortars have virtually no pores inaccessible to water, unlike the mortars with plain Portland cement in which inaccessible pores constitute a significant fraction, growing with the increase in w/b; (ii) with a decrease in w/b the ink-bottle volume decreases. Fraction of this pore type is relatively larger in fly ash mortars; (iii) Siliceous fly ash increased the volume of pores greater than 8 nm, in particular in the group with radii larger than 20 nm at all w/b ratios.