Crystal structures of three complexes of zinc chloride with tri-tert-butylphosphane

Crystal structures of three complexes of zinc chloride with tri-tert-butylphosphane

Under anhydrous conditions and in the absence of a Lewis-base solvent, a zinc chloride complex with tri-tert-butylphosphane as the μ-bridged dimer is formed, viz. di-μ-chlorido-bis[chloridobis(tri-tert-butylphosphane)zinc], [ZnCl4(C12H27P)2], (1), which features a nearly square-shaped (ZnCl)2 cyclic...

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Bibliographic Details
Main Authors: Aaron D. Finke, Danielle L. Gray, Jeffrey S. Moore
Format: Article
Language:English
Published: International Union of Crystallography 2016-01-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
zinc chloride
tri-tert-butylphosphane
Lewis base
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015023373

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