High-efficiency method for recycling lithium from spent LiFePO4 cathode

The extraction of Li from the spent LiFePO4 cathode is enhanced by the selective removal using interactions between HCl and NaClO to dissolve the Li+ ion while Fe and P are retained in the structure. Several parameters, including the effects of dosage and drop acceleration of HCl and NaClO, reaction...

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Main Authors:	Yan Tingting, Zhong Shengwen, Zhou Miaomiao, Guo Xiaoming, Hu Jingwei, Wang Fangfang, Zeng Fantao, Zuo Sicheng
Format:	Article
Language:	English
Published:	De Gruyter 2020-12-01
Series:	Nanotechnology Reviews
Subjects:	lifepo4 li recovery battery-grade li2co3 extraction
Online Access:	https://doi.org/10.1515/ntrev-2020-0119

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record_format	Article
spelling	doaj-4921d6ebb9b84a9497da2d316aecac792021-09-06T19:21:13ZengDe GruyterNanotechnology Reviews2191-90972020-12-01911586159310.1515/ntrev-2020-0119ntrev-2020-0119High-efficiency method for recycling lithium from spent LiFePO4 cathodeYan Tingting0Zhong Shengwen1Zhou Miaomiao2Guo Xiaoming3Hu Jingwei4Wang Fangfang5Zeng Fantao6Zuo Sicheng7Jiangxi Key Laboratory of Power Batteries and Materials, School of Materials Science and Engineering, Jiangxi University of Sciences and Technology, Ganzhou, 341000, ChinaJiangxi Key Laboratory of Power Batteries and Materials, School of Materials Science and Engineering, Jiangxi University of Sciences and Technology, Ganzhou, 341000, ChinaJiangxi Key Laboratory of Power Batteries and Materials, School of Materials Science and Engineering, Jiangxi University of Sciences and Technology, Ganzhou, 341000, ChinaTechnical Research and Development Department, Ganzhou Huajing Rare Earth New Materials Co. LTD, Ganzhou, 341000, ChinaJiangxi Key Laboratory of Power Batteries and Materials, School of Materials Science and Engineering, Jiangxi University of Sciences and Technology, Ganzhou, 341000, ChinaCollege of Chemical Engineering, Fuzhou University, Fuzhou, 350108, ChinaJiangxi Key Laboratory of Power Batteries and Materials, School of Materials Science and Engineering, Jiangxi University of Sciences and Technology, Ganzhou, 341000, ChinaJiangxi Key Laboratory of Power Batteries and Materials, School of Materials Science and Engineering, Jiangxi University of Sciences and Technology, Ganzhou, 341000, ChinaThe extraction of Li from the spent LiFePO4 cathode is enhanced by the selective removal using interactions between HCl and NaClO to dissolve the Li+ ion while Fe and P are retained in the structure. Several parameters, including the effects of dosage and drop acceleration of HCl and NaClO, reaction time, reaction temperature, and solid–liquid ratio on lithium leaching, were tested. The Total yields of lithium can achieve 97% after extraction process that lithium is extracted from the precipitated mother liquor, using an appropriate extraction agent that is a mixture of P507 and TBP and NF. The method also significantly reduced the use of acid and alkali, and the economic benefit of recycling is improved. Changes in composition, morphology, and structure of the material in the dissolution process are characterized by inductively coupled plasma optical emission spectrometry, scanning electron microscope, X-ray diffraction, particle size distribution instrument, and moisture analysis.https://doi.org/10.1515/ntrev-2020-0119lifepo4 li recoverybattery-grade li2co3 extraction
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Yan Tingting Zhong Shengwen Zhou Miaomiao Guo Xiaoming Hu Jingwei Wang Fangfang Zeng Fantao Zuo Sicheng
spellingShingle	Yan Tingting Zhong Shengwen Zhou Miaomiao Guo Xiaoming Hu Jingwei Wang Fangfang Zeng Fantao Zuo Sicheng High-efficiency method for recycling lithium from spent LiFePO4 cathode Nanotechnology Reviews lifepo4 li recovery battery-grade li2co3 extraction
author_facet	Yan Tingting Zhong Shengwen Zhou Miaomiao Guo Xiaoming Hu Jingwei Wang Fangfang Zeng Fantao Zuo Sicheng
author_sort	Yan Tingting
title	High-efficiency method for recycling lithium from spent LiFePO4 cathode
title_short	High-efficiency method for recycling lithium from spent LiFePO4 cathode
title_full	High-efficiency method for recycling lithium from spent LiFePO4 cathode
title_fullStr	High-efficiency method for recycling lithium from spent LiFePO4 cathode
title_full_unstemmed	High-efficiency method for recycling lithium from spent LiFePO4 cathode
title_sort	high-efficiency method for recycling lithium from spent lifepo4 cathode
publisher	De Gruyter
series	Nanotechnology Reviews
issn	2191-9097
publishDate	2020-12-01
description	The extraction of Li from the spent LiFePO4 cathode is enhanced by the selective removal using interactions between HCl and NaClO to dissolve the Li+ ion while Fe and P are retained in the structure. Several parameters, including the effects of dosage and drop acceleration of HCl and NaClO, reaction time, reaction temperature, and solid–liquid ratio on lithium leaching, were tested. The Total yields of lithium can achieve 97% after extraction process that lithium is extracted from the precipitated mother liquor, using an appropriate extraction agent that is a mixture of P507 and TBP and NF. The method also significantly reduced the use of acid and alkali, and the economic benefit of recycling is improved. Changes in composition, morphology, and structure of the material in the dissolution process are characterized by inductively coupled plasma optical emission spectrometry, scanning electron microscope, X-ray diffraction, particle size distribution instrument, and moisture analysis.
topic	lifepo4 li recovery battery-grade li2co3 extraction
url	https://doi.org/10.1515/ntrev-2020-0119
work_keys_str_mv	AT yantingting highefficiencymethodforrecyclinglithiumfromspentlifepo4cathode AT zhongshengwen highefficiencymethodforrecyclinglithiumfromspentlifepo4cathode AT zhoumiaomiao highefficiencymethodforrecyclinglithiumfromspentlifepo4cathode AT guoxiaoming highefficiencymethodforrecyclinglithiumfromspentlifepo4cathode AT hujingwei highefficiencymethodforrecyclinglithiumfromspentlifepo4cathode AT wangfangfang highefficiencymethodforrecyclinglithiumfromspentlifepo4cathode AT zengfantao highefficiencymethodforrecyclinglithiumfromspentlifepo4cathode AT zuosicheng highefficiencymethodforrecyclinglithiumfromspentlifepo4cathode
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High-efficiency method for recycling lithium from spent LiFePO4 cathode

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