Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides

Development of highly active heterogeneous catalysts is an effective strategy for modern organic synthesis chemistry. In this work, acidic mesoporous zeolite ZSM-5 (HZSM-5-M), acidic-free mesoporous zeolite TS-1 (TS-1-M), and basic ETS-10 zeolite supported metal Cu catalysts were prepared to investi...

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Main Authors:	Jun Hu, Chaojie Zhu, Feifei Xia, Zhongxue Fang, Fengli Yang, Jushi Weng, Pengfei Yao, Chunzhi Zheng, Hai Dong, Wenqian Fu
Format:	Article
Language:	English
Published:	MDPI AG 2017-12-01
Series:	Nanomaterials
Subjects:	mesoporous zeolite ZSM-5 copper hydroxysulfurization acidity
Online Access:	https://www.mdpi.com/2079-4991/7/12/459

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spelling	doaj-48774d61e6d6484cb29eb9af14d51ad72020-11-24T21:08:42ZengMDPI AGNanomaterials2079-49912017-12-0171245910.3390/nano7120459nano7120459Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with DisulfidesJun Hu0Chaojie Zhu1Feifei Xia2Zhongxue Fang3Fengli Yang4Jushi Weng5Pengfei Yao6Chunzhi Zheng7Hai Dong8Wenqian Fu9School of Chemical and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, ChinaSchool of Petrochemical Engineering, Changzhou University, Changzhou 213164, ChinaSchool of Chemical and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, ChinaSchool of Petrochemical Engineering, Changzhou University, Changzhou 213164, ChinaSchool of Chemical and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, ChinaSchool of Chemical and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, ChinaSchool of Chemical and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, ChinaSchool of Chemical and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, ChinaSchool of Petrochemical Engineering, Changzhou University, Changzhou 213164, ChinaSchool of Petrochemical Engineering, Changzhou University, Changzhou 213164, ChinaDevelopment of highly active heterogeneous catalysts is an effective strategy for modern organic synthesis chemistry. In this work, acidic mesoporous zeolite ZSM-5 (HZSM-5-M), acidic-free mesoporous zeolite TS-1 (TS-1-M), and basic ETS-10 zeolite supported metal Cu catalysts were prepared to investigate their catalytic performances in the hydroxysulfurization of styrenes with diaryl disulfides. The effect of pore size and acidities of the supports, as well as the Cu species electronic properties of the catalysts on reaction activity were investigated. The results show that Cu+ and Cu2+ binded on HZSM-5-M show the highest activity and product selectivity for the desired β-hydroxysulfides compounds.https://www.mdpi.com/2079-4991/7/12/459mesoporous zeolite ZSM-5copperhydroxysulfurizationacidity
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Jun Hu Chaojie Zhu Feifei Xia Zhongxue Fang Fengli Yang Jushi Weng Pengfei Yao Chunzhi Zheng Hai Dong Wenqian Fu
spellingShingle	Jun Hu Chaojie Zhu Feifei Xia Zhongxue Fang Fengli Yang Jushi Weng Pengfei Yao Chunzhi Zheng Hai Dong Wenqian Fu Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides Nanomaterials mesoporous zeolite ZSM-5 copper hydroxysulfurization acidity
author_facet	Jun Hu Chaojie Zhu Feifei Xia Zhongxue Fang Fengli Yang Jushi Weng Pengfei Yao Chunzhi Zheng Hai Dong Wenqian Fu
author_sort	Jun Hu
title	Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides
title_short	Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides
title_full	Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides
title_fullStr	Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides
title_full_unstemmed	Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides
title_sort	acidic mesoporous zeolite zsm-5 supported cu catalyst with good catalytic performance in the hydroxysulfurization of styrenes with disulfides
publisher	MDPI AG
series	Nanomaterials
issn	2079-4991
publishDate	2017-12-01
description	Development of highly active heterogeneous catalysts is an effective strategy for modern organic synthesis chemistry. In this work, acidic mesoporous zeolite ZSM-5 (HZSM-5-M), acidic-free mesoporous zeolite TS-1 (TS-1-M), and basic ETS-10 zeolite supported metal Cu catalysts were prepared to investigate their catalytic performances in the hydroxysulfurization of styrenes with diaryl disulfides. The effect of pore size and acidities of the supports, as well as the Cu species electronic properties of the catalysts on reaction activity were investigated. The results show that Cu+ and Cu2+ binded on HZSM-5-M show the highest activity and product selectivity for the desired β-hydroxysulfides compounds.
topic	mesoporous zeolite ZSM-5 copper hydroxysulfurization acidity
url	https://www.mdpi.com/2079-4991/7/12/459
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Acidic Mesoporous Zeolite ZSM-5 Supported Cu Catalyst with Good Catalytic Performance in the Hydroxysulfurization of Styrenes with Disulfides

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