Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato}bis[(benzoato-κO)manganese(III)] dihydrate

Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato}bis[(benzoato-κO)manganese(III)] dihydrate

The title compound, [Mn2(C18H18N2O2)2(C7H5O2)2]·2H2O, was synthesized by the reaction between manganese(II) benzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxyacetophenone. The Jahn–Teller-distorted manganese(III) ions of the cent...

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Main Authors: V. S Thampidas, T. Radhakrishnan, Robert D. Pike
Format: Article
Language:English
Published: International Union of Crystallography 2008-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680706446X
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spelling doaj-483498492cc7409ab441b12390678adf2020-11-25T02:14:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m150m15110.1107/S160053680706446XBis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato}bis[(benzoato-κO)manganese(III)] dihydrateV. S ThampidasT. RadhakrishnanRobert D. PikeThe title compound, [Mn2(C18H18N2O2)2(C7H5O2)2]·2H2O, was synthesized by the reaction between manganese(II) benzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxyacetophenone. The Jahn–Teller-distorted manganese(III) ions of the centrosymmetric dimer are connected through phenoxy bridges. Hydrogen-bonding interactions between the uncoordinated C=O of the benzoate and uncoordinated water molecules link the dimers into a chain running parallel to the c axis.http://scripts.iucr.org/cgi-bin/paper?S160053680706446X
collection DOAJ
language English
format Article
sources DOAJ
author V. S Thampidas
T. Radhakrishnan
Robert D. Pike
spellingShingle V. S Thampidas
T. Radhakrishnan
Robert D. Pike
Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato}bis[(benzoato-κO)manganese(III)] dihydrate
Acta Crystallographica Section E
author_facet V. S Thampidas
T. Radhakrishnan
Robert D. Pike
author_sort V. S Thampidas
title Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato}bis[(benzoato-κO)manganese(III)] dihydrate
title_short Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato}bis[(benzoato-κO)manganese(III)] dihydrate
title_full Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato}bis[(benzoato-κO)manganese(III)] dihydrate
title_fullStr Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato}bis[(benzoato-κO)manganese(III)] dihydrate
title_full_unstemmed Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato}bis[(benzoato-κO)manganese(III)] dihydrate
title_sort bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato}bis[(benzoato-κo)manganese(iii)] dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-01-01
description The title compound, [Mn2(C18H18N2O2)2(C7H5O2)2]·2H2O, was synthesized by the reaction between manganese(II) benzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxyacetophenone. The Jahn–Teller-distorted manganese(III) ions of the centrosymmetric dimer are connected through phenoxy bridges. Hydrogen-bonding interactions between the uncoordinated C=O of the benzoate and uncoordinated water molecules link the dimers into a chain running parallel to the c axis.
url http://scripts.iucr.org/cgi-bin/paper?S160053680706446X
work_keys_str_mv AT vsthampidas bis956228242118242ethane12diyldinitrilodiethylidynediphenolatobisbenzoato954omanganeseiiidihydrate
AT tradhakrishnan bis956228242118242ethane12diyldinitrilodiethylidynediphenolatobisbenzoato954omanganeseiiidihydrate
AT robertdpike bis956228242118242ethane12diyldinitrilodiethylidynediphenolatobisbenzoato954omanganeseiiidihydrate
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