Bis{μ-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenolato}bis[(benzoato-κO)manganese(III)] dihydrate
The title compound, [Mn2(C18H18N2O2)2(C7H5O2)2]·2H2O, was synthesized by the reaction between manganese(II) benzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxyacetophenone. The Jahn–Teller-distorted manganese(III) ions of the cent...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680706446X |
| Summary: | The title compound, [Mn2(C18H18N2O2)2(C7H5O2)2]·2H2O, was synthesized by the reaction between manganese(II) benzoate and the Schiff base generated in situ by the condensation of ethane-1,2-diamine and o-hydroxyacetophenone. The Jahn–Teller-distorted manganese(III) ions of the centrosymmetric dimer are connected through phenoxy bridges. Hydrogen-bonding interactions between the uncoordinated C=O of the benzoate and uncoordinated water molecules link the dimers into a chain running parallel to the c axis. |
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| ISSN: | 1600-5368 |