Synthesis and Application of Amin-modified Fe3O4@MCM-41 Core-shell Magnetic Mesoporous for Effective Removal of pb2+ ions from Aqueous Solutions and Optimization with Response Surface Methodology

<span class="CharOverride-24">In this study, a selective, fast and novel magnetic mesoporous silica sorbent Fe</span><span class="CharOverride-25">3</span><span class="CharOverride-24">O</span><span class="CharOverride-25"...

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Main Authors: Kamal Alizadeh, Esmail Khaledyan, Yagoub Mansourpanah
Format: Article
Language:English
Published: Iranian Environmental Mutagen Society 2018-07-01
Series:Journal of Water and Environmental Nanotechnology
Subjects:
Online Access:http://www.jwent.net/article_32101_3a9272c29a7bc6a5f3a74b940653fd3b.pdf
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spelling doaj-48226c2d079743fd8223e78a007eea512020-11-25T02:34:56ZengIranian Environmental Mutagen SocietyJournal of Water and Environmental Nanotechnology2476-72042476-66152018-07-013324325310.22090/jwent.2018.03.00532101Synthesis and Application of Amin-modified Fe3O4@MCM-41 Core-shell Magnetic Mesoporous for Effective Removal of pb2+ ions from Aqueous Solutions and Optimization with Response Surface MethodologyKamal Alizadeh0Esmail Khaledyan1Yagoub Mansourpanah2Department of Chemistry, Lorestan University, Khorramabad, IranDepartment of Chemistry, Lorestan University, Khorramabad, IranDepartment of Chemistry, Lorestan University, Khorramabad, Iran<span class="CharOverride-24">In this study, a selective, fast and novel magnetic mesoporous silica sorbent Fe</span><span class="CharOverride-25">3</span><span class="CharOverride-24">O</span><span class="CharOverride-25">4</span><span class="CharOverride-24">@MCM-41-NH</span><span class="CharOverride-25">2</span><span class="CharOverride-24">,</span><span class="CharOverride-25"> </span><span class="CharOverride-24">was synthesized, functionalized and has been used for the removal of Pb</span><span class="CharOverride-26">+2</span><span class="CharOverride-24"> ions from aqueous solution. The characteristics of the Fe</span><span class="CharOverride-25">3</span><span class="CharOverride-24">O</span><span class="CharOverride-25">4</span><span class="CharOverride-24">@MCM-41-NH</span><span class="CharOverride-25">2</span><span class="CharOverride-24"> sorbent was investigated by XRD, VSM, SEM, TEM, BET, and FT-IR. The response surface methodology (RSM) based on central composite design (CCD) was utilized for estimating the effects of parameters, namely contact time (min), pH, the quantity of adsorbent (g) and initial concentration of Pb</span><span class="CharOverride-26">+2</span><span class="CharOverride-24">. The quadratic model was used as the best model for guessing variables. The results of the analysis of variance for this model were obtained with a high F-value (50.28), very low P-value (<0.0001) and non-significant lack of fit (0.2251). The maximum adsorption capacity was obtained at 46.08 mg/L. Fitting equilibrium data with different isotherm models shows that Freundlich isotherm was the best-fitted model. The pseudo-second-order model was the best model for fitting experimental data.</span> <span class="CharOverride-24"> </span>http://www.jwent.net/article_32101_3a9272c29a7bc6a5f3a74b940653fd3b.pdfadsorptioncentral composite designmagnetic mesoporous silica sorbentpb+2removal
collection DOAJ
language English
format Article
sources DOAJ
author Kamal Alizadeh
Esmail Khaledyan
Yagoub Mansourpanah
spellingShingle Kamal Alizadeh
Esmail Khaledyan
Yagoub Mansourpanah
Synthesis and Application of Amin-modified Fe3O4@MCM-41 Core-shell Magnetic Mesoporous for Effective Removal of pb2+ ions from Aqueous Solutions and Optimization with Response Surface Methodology
Journal of Water and Environmental Nanotechnology
adsorption
central composite design
magnetic mesoporous silica sorbent
pb+2
removal
author_facet Kamal Alizadeh
Esmail Khaledyan
Yagoub Mansourpanah
author_sort Kamal Alizadeh
title Synthesis and Application of Amin-modified Fe3O4@MCM-41 Core-shell Magnetic Mesoporous for Effective Removal of pb2+ ions from Aqueous Solutions and Optimization with Response Surface Methodology
title_short Synthesis and Application of Amin-modified Fe3O4@MCM-41 Core-shell Magnetic Mesoporous for Effective Removal of pb2+ ions from Aqueous Solutions and Optimization with Response Surface Methodology
title_full Synthesis and Application of Amin-modified Fe3O4@MCM-41 Core-shell Magnetic Mesoporous for Effective Removal of pb2+ ions from Aqueous Solutions and Optimization with Response Surface Methodology
title_fullStr Synthesis and Application of Amin-modified Fe3O4@MCM-41 Core-shell Magnetic Mesoporous for Effective Removal of pb2+ ions from Aqueous Solutions and Optimization with Response Surface Methodology
title_full_unstemmed Synthesis and Application of Amin-modified Fe3O4@MCM-41 Core-shell Magnetic Mesoporous for Effective Removal of pb2+ ions from Aqueous Solutions and Optimization with Response Surface Methodology
title_sort synthesis and application of amin-modified fe3o4@mcm-41 core-shell magnetic mesoporous for effective removal of pb2+ ions from aqueous solutions and optimization with response surface methodology
publisher Iranian Environmental Mutagen Society
series Journal of Water and Environmental Nanotechnology
issn 2476-7204
2476-6615
publishDate 2018-07-01
description <span class="CharOverride-24">In this study, a selective, fast and novel magnetic mesoporous silica sorbent Fe</span><span class="CharOverride-25">3</span><span class="CharOverride-24">O</span><span class="CharOverride-25">4</span><span class="CharOverride-24">@MCM-41-NH</span><span class="CharOverride-25">2</span><span class="CharOverride-24">,</span><span class="CharOverride-25"> </span><span class="CharOverride-24">was synthesized, functionalized and has been used for the removal of Pb</span><span class="CharOverride-26">+2</span><span class="CharOverride-24"> ions from aqueous solution. The characteristics of the Fe</span><span class="CharOverride-25">3</span><span class="CharOverride-24">O</span><span class="CharOverride-25">4</span><span class="CharOverride-24">@MCM-41-NH</span><span class="CharOverride-25">2</span><span class="CharOverride-24"> sorbent was investigated by XRD, VSM, SEM, TEM, BET, and FT-IR. The response surface methodology (RSM) based on central composite design (CCD) was utilized for estimating the effects of parameters, namely contact time (min), pH, the quantity of adsorbent (g) and initial concentration of Pb</span><span class="CharOverride-26">+2</span><span class="CharOverride-24">. The quadratic model was used as the best model for guessing variables. The results of the analysis of variance for this model were obtained with a high F-value (50.28), very low P-value (<0.0001) and non-significant lack of fit (0.2251). The maximum adsorption capacity was obtained at 46.08 mg/L. Fitting equilibrium data with different isotherm models shows that Freundlich isotherm was the best-fitted model. The pseudo-second-order model was the best model for fitting experimental data.</span> <span class="CharOverride-24"> </span>
topic adsorption
central composite design
magnetic mesoporous silica sorbent
pb+2
removal
url http://www.jwent.net/article_32101_3a9272c29a7bc6a5f3a74b940653fd3b.pdf
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AT esmailkhaledyan synthesisandapplicationofaminmodifiedfe3o4mcm41coreshellmagneticmesoporousforeffectiveremovalofpb2ionsfromaqueoussolutionsandoptimizationwithresponsesurfacemethodology
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