Bimetallic nickel-molybdenum/tungsten nanoalloys for high-efficiency hydrogen oxidation catalysis in alkaline electrolytes

The lack of efficient and cost-effective catalysts for hydrogen oxidation reaction (HOR) hampers the application of hydroxide exchange membrane fuel cells. Here, authors reported bimetallic MoNi4 and WNi4 nanoalloys with marked HOR activity in alkali, among which MoNi4 outperforms the Pt/C catalyst.

Bibliographic Details
Main Authors: Yu Duan, Zi-You Yu, Li Yang, Li-Rong Zheng, Chu-Tian Zhang, Xiao-Tu Yang, Fei-Yue Gao, Xiao-Long Zhang, Xingxing Yu, Ren Liu, Hong-He Ding, Chao Gu, Xu-Sheng Zheng, Lei Shi, Jun Jiang, Jun-Fa Zhu, Min-Rui Gao, Shu-Hong Yu
Format: Article
Language:English
Published: Nature Publishing Group 2020-09-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-020-18585-4
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author Yu Duan
Zi-You Yu
Li Yang
Li-Rong Zheng
Chu-Tian Zhang
Xiao-Tu Yang
Fei-Yue Gao
Xiao-Long Zhang
Xingxing Yu
Ren Liu
Hong-He Ding
Chao Gu
Xu-Sheng Zheng
Lei Shi
Jun Jiang
Jun-Fa Zhu
Min-Rui Gao
Shu-Hong Yu
spellingShingle Yu Duan
Zi-You Yu
Li Yang
Li-Rong Zheng
Chu-Tian Zhang
Xiao-Tu Yang
Fei-Yue Gao
Xiao-Long Zhang
Xingxing Yu
Ren Liu
Hong-He Ding
Chao Gu
Xu-Sheng Zheng
Lei Shi
Jun Jiang
Jun-Fa Zhu
Min-Rui Gao
Shu-Hong Yu
Bimetallic nickel-molybdenum/tungsten nanoalloys for high-efficiency hydrogen oxidation catalysis in alkaline electrolytes
Nature Communications
author_facet Yu Duan
Zi-You Yu
Li Yang
Li-Rong Zheng
Chu-Tian Zhang
Xiao-Tu Yang
Fei-Yue Gao
Xiao-Long Zhang
Xingxing Yu
Ren Liu
Hong-He Ding
Chao Gu
Xu-Sheng Zheng
Lei Shi
Jun Jiang
Jun-Fa Zhu
Min-Rui Gao
Shu-Hong Yu
author_sort Yu Duan
title Bimetallic nickel-molybdenum/tungsten nanoalloys for high-efficiency hydrogen oxidation catalysis in alkaline electrolytes
title_short Bimetallic nickel-molybdenum/tungsten nanoalloys for high-efficiency hydrogen oxidation catalysis in alkaline electrolytes
title_full Bimetallic nickel-molybdenum/tungsten nanoalloys for high-efficiency hydrogen oxidation catalysis in alkaline electrolytes
title_fullStr Bimetallic nickel-molybdenum/tungsten nanoalloys for high-efficiency hydrogen oxidation catalysis in alkaline electrolytes
title_full_unstemmed Bimetallic nickel-molybdenum/tungsten nanoalloys for high-efficiency hydrogen oxidation catalysis in alkaline electrolytes
title_sort bimetallic nickel-molybdenum/tungsten nanoalloys for high-efficiency hydrogen oxidation catalysis in alkaline electrolytes
publisher Nature Publishing Group
series Nature Communications
issn 2041-1723
publishDate 2020-09-01
description The lack of efficient and cost-effective catalysts for hydrogen oxidation reaction (HOR) hampers the application of hydroxide exchange membrane fuel cells. Here, authors reported bimetallic MoNi4 and WNi4 nanoalloys with marked HOR activity in alkali, among which MoNi4 outperforms the Pt/C catalyst.
url https://doi.org/10.1038/s41467-020-18585-4
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spelling doaj-48072599ff0d436db6b0d563e8ca4e9e2021-09-26T11:46:52ZengNature Publishing GroupNature Communications2041-17232020-09-0111111010.1038/s41467-020-18585-4Bimetallic nickel-molybdenum/tungsten nanoalloys for high-efficiency hydrogen oxidation catalysis in alkaline electrolytesYu Duan0Zi-You Yu1Li Yang2Li-Rong Zheng3Chu-Tian Zhang4Xiao-Tu Yang5Fei-Yue Gao6Xiao-Long Zhang7Xingxing Yu8Ren Liu9Hong-He Ding10Chao Gu11Xu-Sheng Zheng12Lei Shi13Jun Jiang14Jun-Fa Zhu15Min-Rui Gao16Shu-Hong Yu17Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Department of Chemistry, Institute of Biomimetic Materials and Chemistry, University of Science and Technology of ChinaDivision of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Department of Chemistry, Institute of Biomimetic Materials and Chemistry, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale, CAS Center for Excellence in Nanoscience, School of Chemistry and Materials Science, University of Science and Technology of ChinaBeijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of SciencesDivision of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Department of Chemistry, Institute of Biomimetic Materials and Chemistry, University of Science and Technology of ChinaDivision of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Department of Chemistry, Institute of Biomimetic Materials and Chemistry, University of Science and Technology of ChinaDivision of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Department of Chemistry, Institute of Biomimetic Materials and Chemistry, University of Science and Technology of ChinaDivision of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Department of Chemistry, Institute of Biomimetic Materials and Chemistry, University of Science and Technology of ChinaDivision of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Department of Chemistry, Institute of Biomimetic Materials and Chemistry, University of Science and Technology of ChinaDivision of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Department of Chemistry, Institute of Biomimetic Materials and Chemistry, University of Science and Technology of ChinaNational Synchrotron Radiation Laboratory, University of Science and Technology of ChinaDivision of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Department of Chemistry, Institute of Biomimetic Materials and Chemistry, University of Science and Technology of ChinaNational Synchrotron Radiation Laboratory, University of Science and Technology of ChinaDivision of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Department of Chemistry, Institute of Biomimetic Materials and Chemistry, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale, CAS Center for Excellence in Nanoscience, School of Chemistry and Materials Science, University of Science and Technology of ChinaNational Synchrotron Radiation Laboratory, University of Science and Technology of ChinaDivision of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Department of Chemistry, Institute of Biomimetic Materials and Chemistry, University of Science and Technology of ChinaDivision of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Institute of Energy, Hefei Comprehensive National Science Center, CAS Center for Excellence in Nanoscience, Department of Chemistry, Institute of Biomimetic Materials and Chemistry, University of Science and Technology of ChinaThe lack of efficient and cost-effective catalysts for hydrogen oxidation reaction (HOR) hampers the application of hydroxide exchange membrane fuel cells. Here, authors reported bimetallic MoNi4 and WNi4 nanoalloys with marked HOR activity in alkali, among which MoNi4 outperforms the Pt/C catalyst.https://doi.org/10.1038/s41467-020-18585-4