Synthesis and characterization in solution and in the solid State of the palladium aryl bromide complexes [Pd(Ar)Br{(S)-BINAP}]: formation of cyclopalladated complexes and direct observation of a C-N reductive elimination to form heterocycles
The complexes resulting from the 1:4 mixture of [Pd2(dba)3] and P(o-tolyl)3 in benzene react with ortho substituted-arylbromides to generate in situ the corresponding bromide dimer [Pd(Ar)(m-Br){P(o-tolyl)3)}] 2. Addition of 2 equiv. of (S)-BINAP gave the corresponding [PdBr(o-RC6H4){(S)-BINAP}] in...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Sociedade Brasileira de Química
2004-01-01
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| Series: | Journal of the Brazilian Chemical Society |
| Subjects: | |
| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532004000100014 |