Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water

The development of efficient and low-cost catalytic systems is important for the replacement of robust noble metal complexes. The synthesis and application of a stable, phosphine-free, water-soluble cyclopentadienone iron tricarbonyl complex in the reduction of polarized double bonds in pure water i...

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Main Authors:	Daouda Ndiaye, Sébastien Coufourier, Mbaye Diagne Mbaye, Sylvain Gaillard, Jean-Luc Renaud
Format:	Article
Language:	English
Published:	MDPI AG 2020-01-01
Series:	Molecules
Subjects:	iron complexes hydrogen transfer reductive amination alcohols amines
Online Access:	https://www.mdpi.com/1420-3049/25/2/421

id	doaj-47d80571caf347b882b3a3af22035e81
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spelling	doaj-47d80571caf347b882b3a3af22035e812020-11-25T03:32:29ZengMDPI AGMolecules1420-30492020-01-0125242110.3390/molecules25020421molecules25020421Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in WaterDaouda Ndiaye0Sébastien Coufourier1Mbaye Diagne Mbaye2Sylvain Gaillard3Jean-Luc Renaud4Normandie Univ., LCMT, ENSICAEN, UNICAEN, CNRS, 6 boulevard du Maréchal Juin, 14050 Caen, FranceNormandie Univ., LCMT, ENSICAEN, UNICAEN, CNRS, 6 boulevard du Maréchal Juin, 14050 Caen, FranceUniversité Assane Seck de Ziguinchor, BP 523, Ziguinchor, SenegalNormandie Univ., LCMT, ENSICAEN, UNICAEN, CNRS, 6 boulevard du Maréchal Juin, 14050 Caen, FranceNormandie Univ., LCMT, ENSICAEN, UNICAEN, CNRS, 6 boulevard du Maréchal Juin, 14050 Caen, FranceThe development of efficient and low-cost catalytic systems is important for the replacement of robust noble metal complexes. The synthesis and application of a stable, phosphine-free, water-soluble cyclopentadienone iron tricarbonyl complex in the reduction of polarized double bonds in pure water is reported. In the presence of cationic bifunctional iron complexes, a variety of alcohols and amines were prepared in good yields under mild reaction conditions.https://www.mdpi.com/1420-3049/25/2/421iron complexeshydrogen transferreductive aminationalcoholsamines
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Daouda Ndiaye Sébastien Coufourier Mbaye Diagne Mbaye Sylvain Gaillard Jean-Luc Renaud
spellingShingle	Daouda Ndiaye Sébastien Coufourier Mbaye Diagne Mbaye Sylvain Gaillard Jean-Luc Renaud Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water Molecules iron complexes hydrogen transfer reductive amination alcohols amines
author_facet	Daouda Ndiaye Sébastien Coufourier Mbaye Diagne Mbaye Sylvain Gaillard Jean-Luc Renaud
author_sort	Daouda Ndiaye
title	Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water
title_short	Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water
title_full	Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water
title_fullStr	Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water
title_full_unstemmed	Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water
title_sort	cyclopentadienone iron tricarbonyl complexes-catalyzed hydrogen transfer in water
publisher	MDPI AG
series	Molecules
issn	1420-3049
publishDate	2020-01-01
description	The development of efficient and low-cost catalytic systems is important for the replacement of robust noble metal complexes. The synthesis and application of a stable, phosphine-free, water-soluble cyclopentadienone iron tricarbonyl complex in the reduction of polarized double bonds in pure water is reported. In the presence of cationic bifunctional iron complexes, a variety of alcohols and amines were prepared in good yields under mild reaction conditions.
topic	iron complexes hydrogen transfer reductive amination alcohols amines
url	https://www.mdpi.com/1420-3049/25/2/421
work_keys_str_mv	AT daoudandiaye cyclopentadienoneirontricarbonylcomplexescatalyzedhydrogentransferinwater AT sebastiencoufourier cyclopentadienoneirontricarbonylcomplexescatalyzedhydrogentransferinwater AT mbayediagnembaye cyclopentadienoneirontricarbonylcomplexescatalyzedhydrogentransferinwater AT sylvaingaillard cyclopentadienoneirontricarbonylcomplexescatalyzedhydrogentransferinwater AT jeanlucrenaud cyclopentadienoneirontricarbonylcomplexescatalyzedhydrogentransferinwater
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Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water

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