Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water

Cyclopentadienone Iron Tricarbonyl Complexes-Catalyzed Hydrogen Transfer in Water

The development of efficient and low-cost catalytic systems is important for the replacement of robust noble metal complexes. The synthesis and application of a stable, phosphine-free, water-soluble cyclopentadienone iron tricarbonyl complex in the reduction of polarized double bonds in pure water i...

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Bibliographic Details
Main Authors: Daouda Ndiaye, Sébastien Coufourier, Mbaye Diagne Mbaye, Sylvain Gaillard, Jean-Luc Renaud
Format: Article
Language:English
Published: MDPI AG 2020-01-01
Series:Molecules
Subjects:
iron complexes
hydrogen transfer
reductive amination
alcohols
amines
Online Access:https://www.mdpi.com/1420-3049/25/2/421
Description
Summary:The development of efficient and low-cost catalytic systems is important for the replacement of robust noble metal complexes. The synthesis and application of a stable, phosphine-free, water-soluble cyclopentadienone iron tricarbonyl complex in the reduction of polarized double bonds in pure water is reported. In the presence of cationic bifunctional iron complexes, a variety of alcohols and amines were prepared in good yields under mild reaction conditions.
ISSN:1420-3049

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