(Di-2-pyridylamine-κ2N2,N2′)diiodidoplatinum(II)

(Di-2-pyridylamine-κ2N2,N2′)diiodidoplatinum(II)

The PtII ion in the title complex, [PtI2(C10H9N3)], is four-coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and by two I− anions. The dpa ligand is not planar, the dihedral angle between the pyridi...

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Main Author: Kwang Ha
Format: Article
Language:English
Published: International Union of Crystallography 2012-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812011907
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spelling doaj-47c78810d0314877b575b36b3431ad972020-11-25T01:55:04ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m479m47910.1107/S1600536812011907(Di-2-pyridylamine-κ2N2,N2′)diiodidoplatinum(II)Kwang HaThe PtII ion in the title complex, [PtI2(C10H9N3)], is four-coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and by two I− anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 52.8 (3)°. Pairs of complex molecules are assembled through intermolecular N—H...I hydrogen bonds, forming a dimer-type species. The complexes are stacked in columns along the b axis and display several intermolecular π–π interactions between the pyridine rings, with a shortest ring centroid–centroid distance of 3.997 (5) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536812011907
collection DOAJ
language English
format Article
sources DOAJ
author Kwang Ha
spellingShingle Kwang Ha
(Di-2-pyridylamine-κ2N2,N2′)diiodidoplatinum(II)
Acta Crystallographica Section E
author_facet Kwang Ha
author_sort Kwang Ha
title (Di-2-pyridylamine-κ2N2,N2′)diiodidoplatinum(II)
title_short (Di-2-pyridylamine-κ2N2,N2′)diiodidoplatinum(II)
title_full (Di-2-pyridylamine-κ2N2,N2′)diiodidoplatinum(II)
title_fullStr (Di-2-pyridylamine-κ2N2,N2′)diiodidoplatinum(II)
title_full_unstemmed (Di-2-pyridylamine-κ2N2,N2′)diiodidoplatinum(II)
title_sort (di-2-pyridylamine-κ2n2,n2′)diiodidoplatinum(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-04-01
description The PtII ion in the title complex, [PtI2(C10H9N3)], is four-coordinated in a distorted square-planar environment defined by the two pyridine N atoms of the chelating di-2-pyridylamine (dpa) ligand and by two I− anions. The dpa ligand is not planar, the dihedral angle between the pyridine rings being 52.8 (3)°. Pairs of complex molecules are assembled through intermolecular N—H...I hydrogen bonds, forming a dimer-type species. The complexes are stacked in columns along the b axis and display several intermolecular π–π interactions between the pyridine rings, with a shortest ring centroid–centroid distance of 3.997 (5) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812011907
work_keys_str_mv AT kwangha di2pyridylamineamp9542n2n2amp8242diiodidoplatinumii
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