Understanding crystallization pathways leading to manganese oxide polymorph formation

Minor variations in synthesis conditions can redirect crystallization pathways through different nonequilibrium intermediates. Here, the authors present a theoretical framework to predict which polymorphs appear during MnO2 precipitation, which is validated by in situ X-ray scattering of reaction pr...

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Main Authors:	Bor-Rong Chen, Wenhao Sun, Daniil A. Kitchaev, John S. Mangum, Vivek Thampy, Lauren M. Garten, David S. Ginley, Brian P. Gorman, Kevin H. Stone, Gerbrand Ceder, Michael F. Toney, Laura T. Schelhas
Format:	Article
Language:	English
Published:	Nature Publishing Group 2018-06-01
Series:	Nature Communications
Online Access:	https://doi.org/10.1038/s41467-018-04917-y

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spelling	doaj-47c0fc7a94434452b983c298df4c43dd2021-05-11T09:43:57ZengNature Publishing GroupNature Communications2041-17232018-06-01911910.1038/s41467-018-04917-yUnderstanding crystallization pathways leading to manganese oxide polymorph formationBor-Rong Chen0Wenhao Sun1Daniil A. Kitchaev2John S. Mangum3Vivek Thampy4Lauren M. Garten5David S. Ginley6Brian P. Gorman7Kevin H. Stone8Gerbrand Ceder9Michael F. Toney10Laura T. Schelhas11Stanford Synchrotron Light Source, SLAC National Accelerator LaboratoryMaterials Science Division, Lawrence Berkeley National LaboratoryDepartment of Materials Science and Engineering, Massachusetts Institute of TechnologyMetallurgical and Materials Engineering, Colorado School of MinesStanford Synchrotron Light Source, SLAC National Accelerator LaboratoryNational Renewable Energy LaboratoryNational Renewable Energy LaboratoryMetallurgical and Materials Engineering, Colorado School of MinesStanford Synchrotron Light Source, SLAC National Accelerator LaboratoryMaterials Science Division, Lawrence Berkeley National LaboratoryStanford Synchrotron Light Source, SLAC National Accelerator LaboratoryApplied Energy Programs, SLAC National Accelerator LaboratoryMinor variations in synthesis conditions can redirect crystallization pathways through different nonequilibrium intermediates. Here, the authors present a theoretical framework to predict which polymorphs appear during MnO2 precipitation, which is validated by in situ X-ray scattering of reaction progression.https://doi.org/10.1038/s41467-018-04917-y
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Bor-Rong Chen Wenhao Sun Daniil A. Kitchaev John S. Mangum Vivek Thampy Lauren M. Garten David S. Ginley Brian P. Gorman Kevin H. Stone Gerbrand Ceder Michael F. Toney Laura T. Schelhas
spellingShingle	Bor-Rong Chen Wenhao Sun Daniil A. Kitchaev John S. Mangum Vivek Thampy Lauren M. Garten David S. Ginley Brian P. Gorman Kevin H. Stone Gerbrand Ceder Michael F. Toney Laura T. Schelhas Understanding crystallization pathways leading to manganese oxide polymorph formation Nature Communications
author_facet	Bor-Rong Chen Wenhao Sun Daniil A. Kitchaev John S. Mangum Vivek Thampy Lauren M. Garten David S. Ginley Brian P. Gorman Kevin H. Stone Gerbrand Ceder Michael F. Toney Laura T. Schelhas
author_sort	Bor-Rong Chen
title	Understanding crystallization pathways leading to manganese oxide polymorph formation
title_short	Understanding crystallization pathways leading to manganese oxide polymorph formation
title_full	Understanding crystallization pathways leading to manganese oxide polymorph formation
title_fullStr	Understanding crystallization pathways leading to manganese oxide polymorph formation
title_full_unstemmed	Understanding crystallization pathways leading to manganese oxide polymorph formation
title_sort	understanding crystallization pathways leading to manganese oxide polymorph formation
publisher	Nature Publishing Group
series	Nature Communications
issn	2041-1723
publishDate	2018-06-01
description	Minor variations in synthesis conditions can redirect crystallization pathways through different nonequilibrium intermediates. Here, the authors present a theoretical framework to predict which polymorphs appear during MnO2 precipitation, which is validated by in situ X-ray scattering of reaction progression.
url	https://doi.org/10.1038/s41467-018-04917-y
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Understanding crystallization pathways leading to manganese oxide polymorph formation

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